采取纤蛇纹石制备纳米纤维状多孔氧化硅.pdfVIP

第 38 卷第 6 期 中南大学学报自然科学版( ) Vol.38 No.6 2007 年 12 月 J. Cent. South Univ. (Science and Technology) Dec. 2007 采用纤蛇纹石制备纳米纤维状多孔氧化硅 冯其明，杨艳霞，刘 琨，肖 愉，张国范 ( 中南大学 资源加工与生物工程学院，湖南 长沙，410083) 摘 要：以天然纤蛇纹石为原料，通过酸浸制备纳米纤维状多孔氧化硅，并使用X 射线荧光光谱(XRF)、X 射线 衍射(XRD)、傅里叶变换红外光谱(FTIR)和 N2 吸附−脱附等温线技术等对其进行表征。研究结果表明：该多孔氧 化硅具有独特的纳米纤维状形貌；其结构为无定形，结构组成单元仍为硅氧四面体，但四面体交替上下排列，六 2 3 元环结构发生高度扭曲变形。纳米纤维状多孔氧化硅比表面积为 391.8 m /g ，总孔容为 1.05 cm /g ，由吸附−脱附 等温线的滞后回线特征判断其结构中的孔主要为缝隙型孔。 关键词：纤蛇纹石；多孔氧化硅；纳米纤维状；酸浸 中图分类号：TD985; TG321 文献标识码：A 文章编号：1672-7207(2007)06−1088−06 Preparation of porous silica with nanofibrous morphology from chrysotile FENG Qi-ming, YANG Yan-xia, LIU Kun, XIAO Yu, ZHANG Guo-fan (School of Resources Processing and Bioengineering, Central South University, Changsha 410083, China) Abstract: Porous silica with nanofibrous morphology was prepared by acid leaching from natural chrysotile. X-ray fluorescence analysis (XRF), powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and N2 adsorption-desorption techniques were used to characterize the acid-leached products. The results show that the porous silica retains special nanofibrous morphology. The silica is amorphous and its structural unit is a SiO4 tetrahedron and six-member silicon-oxygen rings with the tetrahedral positioned alternately up and down in the six-member rings. The porous silica with nanofibrous morphology produces a high surface area of 391.8 m2/g and total pore volume of 1.05 3 cm /g. The characteristic of hysteresis loop are mainly of slit-shaped por