采取含砷废水沉淀还原法制备三氧化二砷.pdfVIP

第 40 卷第 1 期 中南大学学报( 自然科学版) Vol.40 No.1 2009 年 2 月 Journal of Central South University (Science and Technology) Feb. 2009 采用含砷废水沉淀还原法制备三氧化二砷 郑雅杰，罗 园，王 勇 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：介绍以含砷废水为原料采用沉淀还原法制备三氧化二砷。使用氢氧化钠调节含砷废水 pH 为 6，过滤后 加入硫酸铜，采用氢氧化钠调节 pH 为 8，经沉淀、过滤、洗涤得到绿色亚砷酸铜粉末。使用水将亚砷酸铜调成 浆料，通入 SO 还原、过滤、蒸发、冷却结晶得到白色 As O 。实验结果表明：当水与亚砷酸铜液固比(体积与质 2 2 3 量比)为 4׃1 mL/g，还原时间为 1 h，还原温度为 60 ℃时，亚砷酸铜中砷浸出率达到 89.59%；当还原液pH 为 0， 砷质量浓度为 90 g/L，结晶温度为28 ℃时，得到的产物As O 纯度为 95%，As O 直收率为 80.70%，产物质量 2 3 2 3 达到中国有色金属行业标准(YS−T 99—1997)中的三级标准。 关键词：含砷废水；亚砷酸铜；沉淀；二氧化硫；还原；三氧化二砷 中图分类号：X703 文献标识码：A 文章编号：1672−7207(2009)01−0048−07 Arsenic trioxide made by precipitation-reduction method from As-containing wastewater ZHENG Ya-jie, LUO Yuan, WANG Yong (School of Metallurgy Science and Engineering, Central South University, Changsha 410083, China) Abstract: Preparation arsenic trioxide from As-containing wastewater by precipitation-reduction method was studied. Sodium hydroxide was added in the As-containing wastewater to adjust pH value to 6 and the As-containing wastewater was filtrated. Copper arsenite was obtained by means of precipitation, filtration and washing after copper sulfate was added in the filtrated wastewater and the As-containing wastewater was adjusted to 8. Arsenic trioxide was made by me