用EDTA二酐改性的木材木屑和甘蔗渣去除单一金属水溶液和电镀污水中的Zn2+的处理方案外文翻译原文.docVIP

JournalofHazardousMaterials 176 (2010) 856–863 ContentslistsavailableatScienceDirect Journal of Hazardous Materials journal homepage: /locate/jhazmat RemovalofZn2+fromaqueoussinglemetalsolutionsandelectroplating wastewaterwithwoodsawdustandsugarcanebagassemodi?edwithEDTA dianhydride(EDTAD) FlavianeVilelaPereira,LeandroViníciusAlvesGurgel,LaurentFrédéricGil? DepartamentodeQuímica,InstitutodeCiênciasExataseBiológicas,UniversidadeFederaldeOuroPreto,CampusUniversitárioMorrodoCruzeiro, 35400-000,OuroPreto,MinasGerais,Brazil a r t i c l e i n f o a b s t r a c t Articlehistory: Received26June2009 Receivedinrevisedform2November2009 Accepted22November2009 Available online 27 November 2009 Thisworkdescribes thepreparation ofanewchelating material derivedfromwoodsawdust, Manilkara sp., and not only the use of a new support, but also a chemically modi?ed sugarcane bagasse synthe- sized inourprevious work toremove Zn2+ from aqueous solutions andelectroplating wastewater. The ?rstpartdescribesthechemicalmodi?cation ofwoodsawdustandsugarcanebagasseusingethylenedi- aminetetraaceticdianhydride(EDTAD)asmodifyingagentinordertointroducecarboxylicacidandamine functional groups intothesematerials. Theobtained materials suchasthemodi?ed sugarcane bagasse, EB,andmodi?edwoodsawdust,ESwerethencharacterized byinfraredspectroscopy (IR)andCHN.The secondpartevaluates theadsorption capacity ofZn2+byEBandESfromaqueous singlemetalsolutions andrealelectroplating wastewater, which concentration wasdetermined through direct titration with EDTAandinductively coupled plasma(ICP-OES). Adsorption isotherms weredeveloped usingLangmuir model. Zn2+adsorption capacities werefoundtobe80mg/gforESand105mg/gforEBwhereas forthe industrial wastewater thesevalueswerefoundtobe47mg/gforESand45mg/gforEB.Zn2+adsorption inthewastewater wasfound tobelower thaninZn2+ spiked solution duetothecompetition between othercationsand/orinterference ofotherions,mainlyCa2+andCl?thatwerepresentinthe