增强TMA改性膨润土吸附性能的方法研究.pdfVIP

中国环境科学 2014,34(3) ：638~643 China Environmental Science 增强 TMA 改性膨润土吸附性能的方法研究 程幸荣 1,赵俊波 1,朱润良 1,2*,许 银 1,葛 飞 1 (1.湘潭大学环境工程系,湖南 湘潭 411105 ；2. 中国科学院广 州地球化学研究所,广东 广州 510640) + + 摘要：本研究报道一种增强有机膨润土硅氧烷表面暴露量的新方法:首先将膨润土层间无机阳离子用 Li 交换,然后将 Li 部分被有机阳离 子四甲基铵(TMA)交换(交换量分别为 20%和 60% CEC);接下来通过 180℃热处理 12h 将 Li+迁移进入膨润土片层内, 以降低膨润土电荷密 度. 由于 TMA 的柱撑作用,该方法可有效减少常规减电荷方法导致的膨润土层结构塌陷,因此该方法所制备的减电荷有机膨润土具有更大 的比表面积及更好的 HOCs 吸附性能.其中 TMA 交换量为 20% CEC 的有机膨润土,其比表面积几乎是传统减电荷方法制得有机膨润土比 2 2 表面积的 2 倍(236m /g vs 131m /g),进而增强对硝基苯的吸附能力. 关键词：有机膨润土；减电荷；吸附；有机污染物；水处理 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2014)03-0638-06 1 1 Methods of increasing the adsorption capacity of TMA-bentonites. CHENG Xing-rong , ZHAO Jun-bo , ZHU 1,2* 1 1 Run-liang , XU Yin , GE Fei (1.Department of Environmental Science, Xiangtan University, Xiangtan 411105, China ； 2.Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China). China Environmental Science, 2014,34(3)：638~643 Abstract ：A new method that can increase the exposure of siloxane surface was developed in this work. First the inorganic cations on bentonite were exchanged with Li+, and then a part of the Li+ were further exchanged with tetramethylammonium cation (TMA), i.e., 20% or 60% of the bentonites cation exchange capacity. After that the samples were heated under 180 ℃ for 10h to make sure that most of the Li+ were transferred to bentonite sheets. By this way, the layer charge of bentonites can be effectively reduced while the layers of bentonite can be preserved by pre-exchanged TMA. The resulting o