缩乙二醇甲基丙烯酸双酯的合成及对真丝接枝共聚改性的研究.pdfVIP

一 缠z-甲圣困步E理哗的合成及对弃丝接枝共及改性的研究 SynthesesandapplicationofPolyethyleneglycolDimethacrylates tosilkmodification ABSTRACT Inthisthesis,wediscussthestructureofs giveaview of chemicalmodificationofsilkallovertheworld. suggestthatsilk bemodifiedwithpolyethyleneglycoldimethacrylates Firstofall,wehavedoneaseriesexperimentsto syntheses di-,tri-,tetraethyleneglycoldimethacrylates.Theoptimumconditions ofsynthesesaredetermined,theproductionefficiencyarerespectively 89%,72.5%,60.5%.The puredegreeofdiethyleneglycol dimethacrylatesandtriethylene 70%. glycoldimethacrylatesare90.8, Then silk fibers are processed by polyethyleneglycol dimethacrylateswhichareusedas cross-linkingagents.Withkinetic study,wecountoutgraftingrateequationsandactivation respectively.Theoptimumconditionsaredetermined.The energy processed silk fibers studiedbyinrfared spectrum,theam m o acid are compositions日re measured, nam ic andthedy mechanicalbehaviors arealsodiscussed. 飞study吵atoptimumqualiytsilkfabricaregivenafter modirtedbypolyethylene_glycoldimethacrylates,thesilkfabricsare rimsP，processe件兰y少olyethyleneglycoldimethacrylates,using pad-bakemethod.lbfinddifferentinfluencetofinishedsilkfabrics WAll1黑Adu_1rerentpolyethylene司ycoldimethacrylates,theDCRA, Tv1:{ST-%-ar1-ft_,Lbreaknigsrtength,ayeabilityoffinishedfabricaremeasured. Vvcuurnctertaetnyieneglycoldimethacrylatesisbettertoimprovesilk crease-resistance. WangKe-na(DyeingandFinishingEngineering) Directedby: ProfChenGuo-giang KeyWord: s