BaTiO3粉体的高分子网络凝胶法制备及凝胶化机理的研究.pdfVIP

I37 BaTiO 粉体的高分子网络凝胶法制备及凝胶化机理的研究∗ 3 张林1,2,3 杜景红1,2,3 甘国友1,2,3 严继康1,2,3 易健宏1,2,3 （1.昆明理工大学材料学院，云南省昆明市 650093；2. 稀有及有色金属教育部重点实验室，云南省昆明市 650093；3.云南省新材料制备与加工重点实验室，云南省昆明市 650093 ） 摘要：以BaCO和(C H O) Ti为原料，采用高分子网络凝胶法制备BaTiO 粉体，讨论了PH值、煅烧温度等因素对BaTiO 粉体性能的影 3 4 9 4 3 3 响，并对凝胶化机理进行了研究。通过X射线衍射（XRD）、透射电子显微镜（TEM）、激光粒度分析对粉体性能进行了表征，利用 红外光谱（FTIR）对单体（Ｎ－羟甲基丙烯酰胺）及凝胶体进行分析，结果表明：高分子网络凝胶法制备的BaTiO3粉体颗粒尺寸 小，团聚少，粒度分布均匀。该方法只是通过聚合物水凝胶将无机离子包裹于其中的三维网络结构中，无机离子不参与和凝胶形 成相关的化学反应。 关键词：高分子网络凝胶法；BaTiO3 ；超细粉体；凝胶化机理 The study of using polyacrylamide gel method to prepare BaTiO3 powder and gelation mechanism ZHANG Lin1,2 ,3, DU Jinghong1,2 ,3 , GAN Guoyou1,2 ,3, YAN Jikang1,2 ,3, YI Jianhong1,2 ,3 ( １.Faculty of Materials Science and Engineering Kunming University of Science and Technology; ２.Key lab. of Advance Materials in Rare Precious and Nonferrous Metals, Ministry of Education; ３.P.R China Key lab. of Advance Materials of Yunnan Province, Kunming 650093,China) Abstract: With BaCO and (C H O) Ti as original material, BaTiO was produced with the polyacrylamide gel 3 4 9 4 3 method. The various factors on the performance of powder to determine the optimal process parameters were detailedly discussed, such as quantity of (NH )C H O , PH, calcining temperature in the polyacrylamide gel method. 4 6 5 7 Gelation mechanism was also discussed. Powder properties were characterized by X-ray diffraction (XRD), transmission electron microscopy detection (TEM) and laser particle size analysis. Monomer and Gel was analyzed by infrare