高铋铅阳极泥预处理脱砷研究.pdfVIP

高铋铅阳极泥预处理脱砷研究 李英伟 （云南铜业股份有限公司，云南昆明 650102 ） 摘 要：采用高温碱性浸出，对高铋铅阳极泥中的砷进行脱除预处理研究。试验中考察焙烧温度、液固比、碱浓 度、浸出温度、浸出时间对高温碱浸脱砷效果的影响，确定高温碱性浸出脱砷的最佳工艺条件：焙烧温度 350 ℃， 液固比为 5:1，NaOH 浓度为 150 g/L，浸出温度为 80 ℃，浸出时间为 120 min。在此工艺条件下，As 的浸出率达 到 93 %左右。碱性浸出液经冷却过滤后，补加一定量的 NaOH 返回浸出流程，对 As 的浸出率基本没有影响，实 现了铅阳极泥中 As 与其他有价金属的分离与回收和整个预脱砷工艺的闭路循环。 关键词：有色金属冶金；铅阳极泥；碱性浸出；脱砷 Research on Pre-treatment Processing of Arsenic Removal from Bismuth-rich Lead Anode Slime LI Yingwei ( Yunnan Copper Industry Co., Ltd., Kunming, 650102,China) Abstract: Arsenic was leached from Bismuth-rich Lead Anode Slime using high temperature alkaline leaching processing. The effects of calcination temperature, liquid-solid ratio, concentration of sodium hydroxide, leaching temperature and leaching time were investigated and the optimum conditions of the arsenic removal in the high temperature alkaline leaching processing were determined: calcination temperature at 350 ℃, liquid-solid ratio of 5:1, NaOH concentration of 150 g/L, leaching temperature at 80 ℃ and leaching time for 120 min. About 93 % of the amount arsenic was removed under the conditions. The alkaline leaching solution was returned to leaching processing after cooling, filtrating and adding amount of NaOH, it had no effect on the leaching rate of As, which achieved the effective separation of arsenic from other valuable metals and the closed loop in the arsenic removal processing. Keywords: nonferrous metal Mmetallurgy, lead anode slime, alkaline leaching, arsenic removal 1 引言 在铜冶炼过程中，熔炼时铋、铅、砷、锑进入冰铜，冰铜吹炼时进入烟尘。转炉烟尘经过回收铜和脱 除部分砷后，经过还原熔炼获得粗铅，粗铅电解精炼时铋、铅、砷、锑、锡、金、银进入铅阳极泥。其中， 铋、锑、