从铅阳极泥中制备纳米三氧化二锑粉体的研究.pdfVIP

28 4 武 汉 理 工 大 学 学 报 Vol. 28 No. 4 2006 4 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY Apr . 2006 1, 2 2 2 胡汉祥 , 何晓梅 , 谢华林 ( 1. , 410083; 2. , 421008) : 以铅电解精炼过程中的副产物) ) ) 铅阳极为原料, 通过加入碳粉,使铅阳极泥中的高价锑还原成三 化二锑; 在低压下, 用直接蒸发冷凝的方法制备了纳米三 化二锑此方法无需对铅阳极泥中所含其它成份进行分离, 生产成本 低经XRD 分析, 产品为立方晶型三 化二锑SEM 分析表明, 产品为球形; 粒度分布测定表明: 平均粒度为66 nm, 标 准差( GSD) 为1. 67, 粒度分布均匀; 化学分析表明, 产品中所含三 化二锑大于97. % : 铅阳极泥; 碳粉还原; 三 化二锑; 纳米粉体 : TF 131. 2 : A : 1671-4431(2006) 04-0014-03 Researchon Preparationof Nano eterAnti ony Trioxide fro LeadAnode Sli e 1, 2 2 2 H U H an-x iang , H E X i ao- mei , XIE H ua-li n ( 1. School of Chemistry and Chemical Engineering, Central South University, Changsha 4 10083, China; 2. Department of Chemistry and Chemical Engineering, Hunan Inst itute of Technology, Hengyang 421008, China) Abstract: Nanometer antimony trioxide powder has been prepared by vapor flow condensation from lead anode slime that is a by-production in refining lead by electrolysis without any other separating process. A certain quantity of carbon powder was mixed into the lead anode slime pow der to reduce Sb O to Sb O in the preparing process. The pow ders obtained are pure cubic 2 2 3 antimony trioxide, as determined by XRD, morphology of near spherical shape, as determined by SEM. T he average particle size is 66 nm, geometric standard deviation( GSD) 1. 67, as determined by laser particles sizers. And the content of antimony trioxide powder in the product is larger than 97. % by chemical analysis. Key wo