碱处理PVDF膜接枝苯乙烯的研究99569.pdfVIP

42 , A nhu i A griSciBu ll2009, 15 ( 7) PVDF 宋任远 李东亮 马彩莲 刘 雅 于 媛 ( , 7 10055 ) : 通过溶液接枝聚合法把苯乙烯接枝到碱处理过的聚偏氟乙烯 ( PV DF) 膜上, 氯甲基化后制备了三甲 型离子 交换膜, 研究发现碱处理过的 PVD F 膜容易与苯乙烯发生接枝聚合反应, 且接枝率与碱处理时间呈线性变化关系 FT IR 红外光谱图表明, 处理后的PVDF 膜表面有碳碳双键等基团生成; 用 SEM 对膜表面的微观形貌进行观察, 发现 碱处理前后膜的结构变化不大, 仅是表面变粗糙 : 聚偏氟乙烯; 碱处理; 苯乙烯; 接枝率 TQ 325 A 1007- 77 31( 2009) 07 - 42- 03 Study onA lkalineTreatment of PVDF Membranes onGrafting of Styrene Song Renyuan et a.l ( A rchi ec ure and T echno logy Schoo l o f Sc ience, X i an U niversi y, X i an 710055, Ch ina) Abstract:A new m e hod based on a solu ion g ra f echn ique w as u sed o prepare po ly ( v iny lidene fluor ide) graf ed po ly s y rene m em brane, af er ch lo rome hy la ion prepared rmi e hy lam ine ype ex change m em braneP olys yrene is eas ily g ra f ed in o PVDF, w h ich has been rea ed in KOH so lu ionT here is a linear rela ionship be w een he deg ree o f graf ing and he rea m en mi e in KOH so lu ionT he PVD F and mod if ied m em branes w e re carr ied ou by F our ie r ransform adsorp ion spec rum ( FT IR ) o de erm ine he composi ion o f he m embranesF ur herm ore, he m orpho logy o f he m embranes w ere de erm ined by Scann ing e lec ron m icroscope ( SEM ) , he resul s show ed ha he s ruc ure o f he m em branes w e re no chang ed oo much Key ords: PVDF; a lka line rea m en ; s yrene; g ra f ing 1950 JudaW ); Z- SJ60- 4 ( , , ); ( , ) , 12 PVDF- g- PS , PVDF( TH F) ( [ 1- 3] [ 4] 5 1) , 03 g / 100mL , H ie al Leh inen PVDF , ( BPO), 60 ! ,