成核剂对 PET 结晶行为的影响.pdfVIP

第23 卷 　第3 期 材 　料 　科 　学 　与 　工 　程 　学 　报 总第9 5 期 Vol 2 3 　No 3 Journal of Materials Science Engineering Jun . 2 0 0 5 文章编号 :1004793X( 2005) 成核剂对 PET 结晶行为的影响 史学涛 ,张广成 ,项士新 ,顾军渭 ,刘铁民 ,陈 　挺 ( 西北工业大学理学院应用化学系, 陕西 西安 　710072) ( ) 　　【摘 　要】　采用差示扫描量热仪 DSC 研究了 PET 及添加成核剂后 PET 的非等温结晶过程 ,选用 7 种成核剂和 4 种复合成核剂进行了实验对比研究。结果表明添加任何一种成核剂后 PET 体系的结晶峰温移向高温 ,半结晶时间缩 短 ,结晶速率常数增大 ,结晶度提高。其中有机类成核剂对 PET 结晶改善效果较无机类显著 ,但结晶效果最好的是成核 ( ) 机理为化学成核的高分子类成核剂和复合成核剂。本文还采用了热台偏光显微镜 POM 对 PET 晶体形貌进行了研究 , 发现添加有机成核剂后晶体细微而且密集。 【关键词】　PET; 结晶 ; 成核剂 ; DSC ; HSPOM 中图分类号:O63 , O781 　　　　文献标识码 :A Studies on the Effect of Nucleating Agents to the Crystallization Behavior of PET SHI Xuetao , ZHANG Guangcheng , XIANG Shixin , GU Junwei , LIU Tieming , CHEN Ting ( Chemical Engineering Dept. of North Western Polytechnical University , Xi’an 　710072 , China) 【Abstract 】　The crystallization behavior of polyethylene terephthalate ( PET) and PET nucleating agents blends during the non isothermal crystallization process are studied by DSC technology. The results indicate that the crystal peak shifts to the high temperature zone , the half crystal time t12 shorts , the crystal rate constant increases , and the degree of crystallization also enhances with the addition of nucleating agents. Organic nucleating agents have better crystallization effect than inorganic ones. However macromolecule polymer and the mixed nucleating agents have the best crystallization effect. Also the morphology of PET nucleating system is observed by Polarizing Optical microscope technol