水热法合成在可见光照射下具有高催化活性的纳米TiO_2催化剂_英文_.pdfVIP

25 12 2004 12 Vol. 25 No. 12 Chinese Journal of Catalysis Decembe 2004 Article ID: 0253-9837( 2004) 12- 0925- 03 Communication: 925~ 927 Preparation of Nanosized TiO Catalyst ith High Photocatalytic 2 Activity under Visible Light Irradiation by Hydrothermal Method TANG Peisong, HONG Zhanglian, ZHOU Shifeng, FAN Xianping, WANG Minquan ( Dep artment of Materials Science and Engineering , Zhej iang University, Hangz hou 3 0027, China) Key ords: nanosize, titania, photocatalysis, hyd o the mal method, visible light CLCnumber: O643 Document code: A T he semiconduct o T iO2 is t he most impo t ant and a L ambda 20 U V-Vis spect omete , espect ively. phot ocat alyst fo t he deg adat ion of pollut ant s. Diff use eflectance spect a ( DRS) we e measu ed by Anatase T iO2 has a la ge band gap of 32 eV t hat e- PELA- 1020 w it h an int eg at ing sphe e accesso y in a qui es powe ful UV light t o initiat e t he photocataly tic L ambda 900 U V-Vis spect omet e . T he phot o- eactions. Many modif icat ion methods such as met al catalyt ic expe iment s w e e ca ied out in a self- assem- ion doping, composit e semiconducto s and metal laye bled inst ument w ith a metal halog en lamp ( HQI- modif icat ion have been used t o ext end the light ab- BT , 400W/ D, OSRAM , Ge man) as the i adiat ion so pt ion of the catalyst to t he v isible lig ht