A-O-39_基于粒群衡算的环管反应器中聚丙烯颗粒粒径分布影响因素的分析.pdfVIP

基于粒群衡算的环管反应器中聚丙烯颗粒粒径分 布影响因素的分析 ANALYSIS ON INFLUENCING FACTORS OF PARTICLE SIZE DISTRIBUTION IN PROPYLENE POLYMERIZATION LOOP REACTOR BASED ON PARTICLE POPULATION 正鸿，苏培林，王 炜，温少桦 LUO Zheng-hong, SU Pei-lin, WANG Wei, WEN Shao-hua （厦门大学 化学工程与生物工程系，福建 厦门 36 1005 ） (Depa rtment of Chemical and Biochemical Engineering,X iamen University,X iamen 36 1005, China) 摘要:在液相本体法环管反应器聚丙烯生产过程中，聚丙烯颗粒粒径分布影响聚合速率、气力输送、后处理工序生 产成本和最终的聚丙烯物性，特别是对后续工序有流化床烯烃共聚的工艺有重要影响。为预 环管反应器中聚丙 烯的粒径分布，考察各操作变量和动力学参数对聚丙烯粒径分布的影响，运用了粒群衡算方法。在综合分析环管 反应器中物料流型、聚丙烯颗粒动力学和聚丙烯颗粒生长的基础上，建立了稳态操作时聚丙烯颗粒粒径分布预 模型。模型计算结果表明，当单一粒径催化剂进料时，随着催化剂粒径或是预聚合与主聚合反应温度的增加，聚 丙烯粒径分布向大粒径方向偏移，且分布变宽；相比于反应温度，催化剂粒径作用更为显著。同时发现，丙烯进 料流速对聚丙烯粒径分布的影响很小。在催化剂粒径有分布的情况下，不同粒径催化剂的质量比不但影响聚丙烯 的平均粒径，而且也影响其粒径分布曲线，并在一定的质量比下会出现双峰颗粒粒径分布曲线。 关 键 词: 聚丙烯； 环管反应器；粒径分布；粒群衡算；模型 中图分类号：O643.32 文献标识码：A Abstract: In a propylene polymerization loop reactor, polymerization rate, fluid transport, and cost of post-treatment after polymeric process and polymer properties may be affected by polymer particle size distribution, especially when a co-polymerization technology including olefin polymerization fluidized-bed reactor is followed. In order to investigate the effects of operation parameters and kinetics parameters on the polypropylene particle size distribution in the loop reactor, a steady-state particle size distribution model was developed, in which the flow type in the loop reactor, polypropylene particle dynamics and the particle growth were taken synthetically into account based on the mass balance and solid population balance. The result showed that for uniform size catalyst feed, by increasing either initial catalyst size or the reaction temperature of the main polymeric reactor, t