酰基二茂铁肟的合成及其抗氧化活性研究.pdfVIP

2 8 6 ( ) V ol 28 N o 6 2006 12 J of China T hree Go rg es U niv, ( N atural Sciences) Dec 2006 廖全斌 涂志英 刘明国 陈百玲 ( 三峡大学 化学与生命科学学院, 湖北宜昌 443002) : 合成了酰基二茂铁肟, 通过红外光谱元素分析质谱对结构进行了表征 利用二苯代 味肼 基自由基( DP PH ) 研究了它们及前体化合物的抗氧化活性, 结果表明, 酰基二茂铁及其肟都具有 一定的抗氧化活性, 抗氧化活性随浓度的增大而增强, 随着烷基碳链的增长, 抗氧化活性递减, 酰 基二茂铁肟的抗氧化活性比酰二茂铁的抗氧化活性弱 : 酰基二茂铁肟; 抗氧化活性; DPPH : O627 8+ 1 : A : 1672- 94 8X( 2006) 06- 0566- 04 Synthesis and Antioxidant Activity of Acylferrocene Oxime L iao Quanbin T u zhiying L iu M inggu o Chen Bailin g ( College of Chemistr y L ife Science, China T hree Gorg es U niv , Y ich ang 443002, China) Abstract A cylf errocene o xime w as sy nt hesized and ch aract er iz ed by IR, element analysis , 1H N MR and mass spect ro metry T he ant iox idant act ivity of the acylf err ocene ox ime and it s pr ecur sor w ere ex plo red w it h DPP H It is fo und t hat the acylf er rocene and it s ox ime bot h had cert ain ant iox idant act ivit y and w hich w ould be enhanced w ith t he increase of concentr at ion , but decreased w it h t he increase in t he carbon ch ain leng th T he antiox idant act ivit y o f acylf errocene ox ime is low er th an t h at of acy lferrocene Keywords acylf err ocene ox im e; antiox idant act ivit y; DPP H ( A R) , ( A R) , ( A R) , [ 1- 6] ( A R) , DP PH ( A R) , 1 2 , , 1 2 1 ( A 1) [ 7] , 124 5 ( ) 1 1 2 2