Au催化剂论文：负载型Au催化剂的制备及其在肉桂醛选择性加氢反应中的应用研究.docVIP

Au催化剂论文：负载型Au催化剂的制备及其在肉桂醛选择性加氢反应中的应用研究 【中文摘要】负载型纳米Au催化剂在许多化合物的 【英文摘要】Supported gold catalysts are a kind of promising catalysts for selective hydrogenation based on their good activity and selectivity for the reduction of many compounds.In this paper, using several metal oxides doped TiO2 as supports, which were prepared by the sol-gel method, a series of gold catalysts were prepared by the deposition-precipitation （DP） method. Additionally, a series of Au/La（OH）3 catalysts were prepared by cocipitation （CP） method. All the catalyst were tested in cinnamaldehyde hydrogenation. Their phisico-chemical properties were investigated by XRD, TEM, XPS, BET and TPR techniques. The reaction conditions of cinnamaldehyde selective hydrogenation were optimized.The results show that the performance of Au/TiO2 catalyst is influenced by the type and the content of additives. Among the metal oxide promoters tested, La2O3 modified Au/TiO2 shows the best selectivity for the reduction of carbon-carbon double bond in cinnamaldehyde. The moderate amount of La2O3（10 wt%） can obviously improve the catalytic activity and selectivity of Au/TiO2 for cinnamaldehyde hydrogenation. The presence of La2O3 in TiO2 restrains the growth of TiO2 crystallites, increases the surface area of catalysts and makes the particle size distribution of Au crystallites more evenly. The gold on the surface of Au/TiO2 exists mainly as Au0, but on the La2O3 doped catalyst there is a small portion of Au3+ species besides Au0, which may benefit the activation of the C=O bond of cinnamaldehyde.The results show that La（OH）3 supported gold catalyst shows high selectivity for the reduction of carbon-carbon double bond. With the characterization results, the reason of the high selectivity is that the supporter La（OH）3 and Au interact to form a unique structure. The preparation conditions of Au/La（OH）3 catalyst are optimized as follows: 2 wt% of gold content, calcination temperature 100°C and reduction temperature 150°C.Th