用于马来酸二甲酯选择性加氢的铜基催化剂的制备及表征.pdfVIP

复旦大学硕士学位论文 Abstract Abstract Greatinteresthasbeenarousedduetothe demandfor steadily growing is usedasa materialfor and widely 1，4-butanediol(BDO)whichstarting polymers solvents．The other polybutylene polyurethances terephthalate(PBT)andproduced fromBDOhad asstructuraland an superior properties engineeringplastics．andplay rolein the important fields．Tetrahydrofuran(nⅡ)，obtained many through of an solventfor andamonomer dehydrationBDO，isindispensablemanypolymers inthemanufactureof ether glycol(PBD，etc．Atpresent，Davy polytetramethylene hasshowed for BDOnot thelower process greatadvantageproducing only operation fixed-bed couldbe alsobecausewell—establishedreactor pressure，but technology couldbe tofit distribution themarket utilized．Moreover，theproducts regulated demand as maleatereactant． usingdialkyI The Cu-B were with supportedcatalystspreparedimpregnation·reduction methodfor of Cu-B hydrogenolysisdimethylmaieate．)-A1203 catalyst supported