杭州地区水域中PAEs分布特征及黄颡鱼体内残留消除研究.docVIP

杭州地区水域中PAEs分布特征及黄颡鱼体内残留消除研究 胡天宇1，胡华军1，韩宝瑜2，葛建1,2①，姚元发1，杨丛军1，王敏君1, 屈叶青1，袁萍1 ( 1. 中国计量学院杭州310018; 2. 浙江省生物计量及检验检疫技术重点实验室, 杭州 310018气相色谱(GC)检测技术，对杭州城区水体中种PAEs类化合物进行，确定杭州城区水体PAEs分布特征并PAEs在鱼。研究，杭州水中PAEs化合物含量差异较大，其中DEHP含量。PAEs类化合物在鱼组织中分布，其中脑和肌肉中的消除半衰期范围17h~32h之间。结果表明，PAEs在杭州城区水体中广泛分布，在鱼体中消除缓慢。 X503.225 Studies on distribution characteristics and elimination of PAEs in the water of Hangzhou and Darkbarbel Catfish (Pelteobagrus vachelli.) HU Tian-Yu1, HU Hua-Jun1, HAN Bao-Yu2, GE Jian1,2, YAO Yuan-Fa, YANG Cong-Jun, WANG Min-Jun1, QU Ye-Qing1, YUAN Ping1 （1. College of Life Sciences, China Jiliang University, Hangzhou, 310018; 2. Zhejiang Provincial Key Laboratory of Biometrology and Inspection Quarantine, China Jiliang University, Hangzhou, 310018） Abstract: A GC method was established for simultaneous determination of five PAEs chemicals in water and in fish tissues, which was used to study the PAEs distribution characteristics in water of Hangzhou District and elimination rule in darkbarbel catfish, Pelteobagrus vachelli. And the detection results showed that there were significant differences about PAEs chemicals distribution in different districts of Hangzhou and the content of DEHP was the highest in all the districts of Hangzhou. Then five PAEs chemicals were widely distributed in edible tissues of darkbarbel catfish such as muscle and brain. And their elimination half-times lie between 17h and 32h in muscle and brain. Therefore, all the above results showed that five PAEs chemicals were widely distributed in the different areas of Hangzhou District and slowly eliminated from darkbarbel catfish. Key words: Darkbarbel Catfish; PAEs Chemicals; distribution Characteristics; Elimination Rule; GC-FID 邻苯二甲酸酯类（Phthalic Acid Esters，简称PAEs，别名酞酸酯）是一类重要的有机化合物，主要用于塑料增塑剂、农药、涂料、印染、化妆品、油漆和香料的生产，在自然界中普遍存在（吴平谷等，1999；林兴桃等，2004；陈珠灵等，2007；杨琼等，2008）。近年来研究发现PAEs类化合物是一类环境内分泌干扰物，具有雌激素样活性，它能对生物的正常行为及生殖、发育相关的正常激素的合成、贮存、分泌、体内输送、结合以及清除等过程产生障碍，因此PAEs类化合物在环境中的富集、随食物链迁移将成为水生动物乃至人类的潜在威胁（Mee