铝电解槽氧化铝浓度控制过程分析.docVIP

铝电解槽氧化铝浓度控制过程分析 曹阿林1,2,3，曹斌1,3，易小兵1,3，李劼2 （1.贵阳铝镁设计研究院有限公司，贵阳 550081；2.中南大学 冶金科学与工程学院，长沙 410083；3.国家铝镁电解装备工程技术研究中心，贵阳 550081） 摘要：对铝电解槽氧化铝过（欠）量下料过程中氧化铝浓度变化规律以及对槽电压、电解质温度的影响进行分析结果表明：一定条件下，过（欠）量下料持续时间均随氧化铝浓度变化范围的增大而增大，随过（欠）量百分数的增大而减小，过量下料持续时间随二次反应率的增大而减小，欠量下料持续时间随二次反应率的增大而增大；相同条件下，欠量下料持续时间大于过量下料；一定条件下，槽电压随下料过（欠）量百分数的增大而增大，电解质温度变化量随下料欠量百分数的增加而降低，随下料过量百分数的增加而增加。 关键词：铝电解槽；氧化铝浓度；过（欠）量下料；控制中图分类号：TF81 文献标志码：A 文章编号：1007-7545（2013）0-0000-00 Analysis of Alumina Concentration Control in Aluminum Electrolytic Bath CAO A-lin1,2,3, CAO Bin1,3, YI Xiao-bing1,3, LI Jie2 (1. Guiyang Aluminium-Magnesium Design Research Institute Co., Ltd., Guiyang 550081, China; 2. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China; 3. National Engineering and Technology Research Centre for Aluminium Magnesium Electrolysis Facilities, Guiyang 550081, China) Abstract: Variation of alumina concentration during overfeeding or underfeeding operation and its effects on cell voltage and electrolyte temperature were studied. The results show that the overfeeding or underfeeding operation period extends with increase of alumina concentration variation and shortens with increase of overfeeding or underfeeding percentage, while overfeeding operation period shortens with rise of aluminum oxidation reaction rate and underfeeding operation period extends at the fixed condition. The period of underfeeding operation is longer than that of overfeeding operation. The cell voltage increases with the increase of overfeeding or underfeeding percentage. Variation of electrolyte temperature drops with increase of underfeeding percentage and rises with increase of overfeeding percentage at the fixed condition. Key words: aluminium electrolytic cell; alumina concentration; overfeeding/underfeeding; control 铝电解生产实践与理论研究表明，要获得理想的经济技术指标，必须使铝电解槽处于理想的物料平衡与能量平衡状态下稳定运行，减小引起电流效率损失的二次氧化反应。由于氧化铝的添加是引起物料平衡变化的主要因素，必须使氧化铝浓度维持在一个很窄的范围内，才能避免产生炉底沉淀和发生阳极效应，保证铝电解槽的高效稳定运行[1-3]。 现代大型预焙铝电解槽下料控制系统