MEMO改性硅溶胶增强甲基硅树脂薄膜结构及性能.pdfVIP

维普资讯 化 工 进 展 2007年第26卷第 7期 CHEM ICALINDUSTRYAND ENGINEERING PROGRESS ·985 · MEMO改性硅溶胶增强甲基硅树脂薄膜结构及性能 陆静娟，郭兴忠，杨 辉 (浙江大学材料与化工学院，浙江 杭州 310027) 摘 要：以甲基三 甲氧基硅烷 (MTMS)水解聚合产物作为成膜材料，甲基丙烯酰氧基丙基三甲氧基硅烷 (MEMO) 改性硅溶胶为无机增强剂，采用溶胶一凝胶法在聚碳酸酯 (PC)表面制备透明硅溶胶增强甲基硅树脂薄膜；探讨 了MEMO改性硅溶胶前后涂膜液的稳定特征及薄膜特性，采用envelope方法计算了薄膜厚度。研究结果表明， MEMO改性硅溶胶增强硅树脂涂膜液与未经MEMO改性的涂膜液相比，凝胶时间延长，稳定性提高，易制备厚 膜而不开裂；薄膜对PC片有增透作用，MEMO改性对薄膜增透性能及硬度影响不大；薄膜厚度随着陈化时间的 延长而增加，理论计算所得的膜厚与SEM实测结果相近。 关键词：改性硅溶胶；甲基硅树脂；薄膜性能 中图分类号：TQ50．4 文献标识码：A 文章编号：1000—6613(2007)07—0985—06 Structureandpropertiesofhybridmethylsiliconefilm withsilicasol functionalizedbyMEM O LUJingjuan，GUOXingzhong，YANGHui (SchoolofMaterialsScienceandChemicalEngineering， ZhejiangUniversity，Hnagzhou310027，Zhejiang，China) Abstract：W im polyc0ndensatesofmethyltrimemoxysilane (MTMS) ascoatingmaterials，silicasol modifiedby3一(methacryloxypropy1)一trimethoxysilane(MEMO)asinorganicstrengtheningmaterials， thetransparentsilicasolmodifiedmethylsiliconefilm wasprepraedonpolycrabonate(PC)bythe sol—ge1method．Thepropertiesofthecoatingsolutionandfilm withandwithoutM EM Owerestudied． Thefilm thicknesswascalculatedby theenvelopemethodand compraedwith SEM results．The resultsshowedthattheadditionofMEM O couldextend gelationtimeand improvestabilityofthe coatingsolutionandform thickercrack—freefilm withease．Thefilm improveedthetransparencyof PC．Theaddition ofM EM O hadno effecton reflection—reducingproperty andhradness．Thefilm thickness increased with ageing time．The thicknesscalculated theoretically wasclose to that measuredbySEM ． Keywords：modifiedsilicasol：methv1si1icOneresin；film properties