电致变色材料聚苯胺_邻胺基苯甲酸的合成条件及性能的研究.pdfVIP

PACKAGING ENGINEERING V ol. 28 No. 4 2007. 04 电致变色材料聚苯胺-邻胺基苯甲酸的合成条件及性能的研究 1 2 汤琪 , 王成章 ( 1. , 400074; 2. , 400039) : 聚苯胺-邻胺基苯甲酸是一种溶解性能好的电致变色材料探讨了单 摩尔分数单 浓 度氧化剂用量反应时间反应温度及酸度对聚苯胺-邻胺基苯甲酸性能的影响得出在苯胺与邻胺 基苯甲酸摩尔分数为 2 B 1时, 制得溶解性和电致变色性都很好且产率较高的聚苯胺-邻胺基苯甲酸 的较佳反应条件为: 盐酸浓度为 1. 2 m ol/L 左右, 反应时间为4 ~ 6h, 反应温度为 20~ 25e , 单 浓度 为 0. 4m ol/L 左右, 氧化剂和单 摩尔浓度之比为 1 B 1 : 聚苯胺-邻胺基苯甲酸; 电致变色性; 溶解性; 合成条件 : TQ325. 2 : A : 100 1- 3563( 2007) 04- 0004- 03 S tudy on Synthesis C ond itions and P roperties o f E lectroch rom ic M a teria ls: P olyaniline-co-o-an thran ilic 1 2 TANG Q i , WAN G Cheng-zhang ( 1. Chongq ing iaotong Un iv ers ity, Chongq ing 400074, China; 2. W eather ing T est and Research Center of Sc ience T echnology and Industry for N ational Defense, Chongq ing 400039, Ch ina) Ab stract: P olyaniline-co-o-anthranilic is a good soluble electrochrom icm ater ia.l Some factors influen- c ing the properties of polyan iline-co-o-anthran ilic were discussed, such as m onom er ratio, monom er concen- tration, the am ount of ox idant, reaction tmi es, reaction tem perature, and acid concentration. T he resu lts showed that that when mole ratio bewt een aniline and an isidine is 2 B 1, better reaction cond itions of synthe- s izing polyaniline-co-o-anthranilic w ith good solub ility, electrochrom ism and h igh y ield is as follow s: ac id concentration is 1. 2m ol/L, reaction tmi es is 4~ 6h, reaction temperature is 20~ 25e , m onom er concentra-