提高磷石膏基水泥早期性能研究.docVIP

提高磷石膏基水泥早期性能的研究 冯旭光 辽宁工程技术大学1.51.5 1.51.5作者单位 摘要： 关键词： 中图分类号：?????  Improving the realy perforfornance of phosphogypsum-base cement Xuguang Feng Authors Address Abstract: By means of phosphogypsum(PG) preprocessing and ultra fine grinding of portland clinker addition,the methods of improving the early performance of phosphogypsum-base cemen(PBC) were studied.the hydration mechanism of the cement was also discussed with XRD and SEM .The results showed that the early strength and setting time of PBC would beimproved by modifying PG with steel slag or using ultra fine clinker as alkali activator. The 7d compressive strength of PBC would be more than 10MPa and the 28d compressive strength would reach 49MPa if the measurements were applied simultaneously. The retarding soluble impurities of PG were solidified by steel slag. The hydration of clinker and would accelerata by ultra fine griding of clinker,and early hydration properties PBC were also improved. Key word:phosphogypsum;slag;preprocessing;ultra fine grinding First author抯 address: Liaoning Technical University Liaoning,Fuxin,China Key words: phosphogypsum;slag;preprocessing;ultra fine grinding  引言 。 原状磷石膏：取烘干后的磷石膏在试验小磨中粉磨至比表面积495 m2/kg备用。 预处理磷石膏：掺入占原状磷石膏质量2%的钢渣及50%的水搅拌均匀，静置24h后，于80℃下烘干24h，然后在试验小磨中粉磨5min，测得比表面积为512 m2/kg。 分别取原状磷石膏和预处理磷石膏100g，加入50mL水搅拌均匀，然后真空抽滤，将滤液用PHS-25型pH计测出其pH值分别为4.20和11.30。 超细熟料粉：取5kg水泥熟料在试验小磨中粉磨2h，测得比表面积为734 m2/kg，放置于干燥器中储存。 各个试样的配比及标准稠度用水量、凝结时间和强度测定结果见表2，其中标准稠度用水量、安定性和凝结时间按照GB/法测定：胶砂强度按照GB/T17671-1999测定，各试样的沸煮法安定性测定结果均为合格。 将测定标准稠度用水量的浆体在塑料袋中密封，与强度测定试块在相同条件下养护，在3d、7d和28d龄期从硬化浆体中部取样，在无水乙醇中浸泡终止水化后，在35℃下烘干1h，惊醒XRD和SEM测定。 XRD采用D/Max-RB型转靶X射线衍射仪进行测定。SEM采用JSM 5610LV型扫描电镜进行测定。 2、结果与分析 2.1 预处理磷石膏对水泥性能的影响 对比表中C1~C4试样和CP1~CP4试样的凝结时间测定结果可见，在相同配比的情况下，磷石膏经2%钢渣处理后，水泥的初凝时间缩短了30%左右，终凝时间也有所改善，并且随熟料掺量的增加，水泥凝结时间不短缩短。由表中C、CP和SC系列的强度测定结果可见，同系列试样的3d、7d强度都随着熟料掺量的增加而增大，而28d强度则随着熟料掺量的增加先增大后减小，在熟料掺量为4%时达到最高。这与前期研究结果一致：在磷石膏—矿渣胶宁体系中，碱性激发剂必须适量。 C、CP系列试样的3d抗折和抗压强度对比见图1。由图1可见，磷石膏经钢渣预处理后，