氯化法偏钛酸水解试验研究.docVIP

氯化法偏钛酸的水解试验研究 樊艳金，詹海鸿，谢营邦，柯剑华，满露梅 (广西冶金研究院，南宁 530023) 摘要：以氯化钛液为原料，考察H+和Ti4+浓度、反应温度时间对氯化法偏钛酸水解率及其粒径的影响。结果表明随H+浓度的增大，偏钛酸的水解率粒径先增大后；Ti4+浓度对偏钛酸的水解率影响不大，但增大Ti4+浓度有利于偏钛酸晶核的成长；反应温度有利于偏钛酸的水解及其晶核的长；随着水解时间的增加，偏钛酸的水解率逐渐增加，对偏钛酸粒径的影响甚微。在H+浓度1.2 g/L、Ti4+浓度0 g/L、水解温度108 ℃、水解时间2.5 h的最佳条件下得到呈片状团聚体粒径2~10 μm偏钛酸关键词：氯化钛；偏钛酸；水解；粒径分布 中图分类号：TF823 文献标志码：A 文章编号：1007-7545（2014）10-0000-00 Hydrolysis Study o Metatitanic in Chlorination Process FAN Yan-jin, ZHAN Hai-hong, XIE Ying-bang, KE Jian-hua, MAN Lu-mei (Guangxi Research Institute of Metallurgy, Nanning 530023, China) Abstract: The effects of concentration of H+ and Ti4+, reaction temperature and time on hydrolysis rate and particle size distribution of metatitanic were studied with titanium chloride solution as raw material. The results show that the hydrolysis rate and particle size of metatitanic rise first then decrease with increase of H+ concentration. Concentration of Ti4+ has little effect on hydrolysis rate of metatitanic but in favor of the growth of metatitanic nucleus. Increasing reaction temperature is conducive to promote metatitanic hydrolysis reaction and growth of metatitanic nucleus. Hydrolysis rate of metatitanic rises with increase of time. Hydrolysis time has little effect on particle size of metatitanic. Flake aggregated metatitanic with particle size of 2~10 μm is prepared under the optimum conditions including H+ concentration of 1.2 g/L, Ti4+ concentration of 20 g/L, hydrolysis temperature of 108 ℃, and hydrolysis duration of 2.5 h. Key words: titanium chloride; metatitanic; hydrolysis; particle size distribution 目前，国内钛白粉的生产方法主要是硫酸法[1]。钛白粉颗粒的形貌、粒径和粒径分布对其性能有重要影响，而这些因素在很大程度上取决于前驱体偏钛酸的颗粒形状[23]。因此，偏钛酸的水解条件控制是硫酸法钛白粉生产中非常关键的一步[4]。 迄今为止，国内学者对硫酸法钛白粉生产中的偏钛酸水解做过很多研究，包括钛浓度、水解温度、水解时间、加热方式、搅拌速度等[2,]，但是未见对氯化法水解条件研究的报道。本文以目前硫酸法偏钛酸水解的工艺条件为基础，研究H+浓度、Ti4+浓度、水解温度、水解时间等对氯化法偏钛酸的水解率及粒径分布的影响。 1 试验部分 1.1 试验原料 试验原料取自中的钪富集渣的盐酸溶解液，料液成分g/L）：H+ 0.3~4.0、Fe2+ 0.5~0.7、Ti4+ 25~50、Cl- 10~142、Sc3+ 0.3~0.5、Zr4+ 3~6。 1.2 分析方法 用optima8000型ICP-OES分析各