微波消解原子荧光光谱法快速测定食品中汞和砷的方法研究.pdfVIP

20 10 年第2 期 王铁良, 司敬沛, 贾 斌, 张 玲 ( , 450002) : 建立了一种采用微波消解一次样品前处理原子荧光法依次快速测定食品中汞和 的方法 通过条件优化, 该方法汞和 的检出限分别为0. 023 Lg L 0. 119Lg L ; 试样测定精密度( RSD) , 汞 和 分别为6. 2% 3. 3% ; 加标回收率, 汞和 分别在 96. 0% ~ 105. 0% 95. 9% ~ 102 . 5% 标准 物质测定结果符合要求该法简便快速灵敏, 能够满足食品的检测要求 : 微波消解; 原子荧光光谱法; 食品; 汞; : T S2071 3 : A : 1004- 326 8( 20 10) 02- 0 128- 04 Rapid Det ermination of M ercury and Arsenic in Food by At omic Fluor escence Spect rom etr y w it h M icr ow ave Digest ion WA N G T ie- liang , SI J ing- pei, J IA Bin , ZH A N G Ling ( Research Center of A g ricultura l Q ua lity Standards and T esting T echniques, H enan A cademy of A gr icultural Sciences, Zhengzhou 450002, China) Abstract : In t he paper, a m icrow ave dig estio n- at om ic f luo rescence spect romet er met hod f or rapid- ly det ermining the mercury and arsenic in foo d w as est ablished. By opt imizing t he condit io ns ( i. e. m icrow ave digest ion pre- t reat ment) , t he det ect io n limit s o f mercury and ar senic w er e 01023 Lg L and 01 119 Lg L, respect ively. T he r elat ive st andard deviatio ns of sample det erminat ion ( RSD) of mercury and arsenic w er e 6. 2% and 3. 3% , respect iv ely . T he recovery rat e of samples for mercur y and ar senic w ere 96. 0% - 105 . 0% and 95. 9% - 10215% , respectively. T he t est ing results w it h standard m at erial met t he r equirement s . T his m et hod was simple, rapid and sensi- t ive, and co uld m eet t he t est ing requirem ent s of f ood. Key words: M icrow ave digest ion ; A t om ic fluorescence spect romet ry; F ood;