介孔Ni-CeO2逆水煤气变换催化剂的研究【毕业论文】.docVIP

本科毕业论文 （20 届） 介孔Ni-CeO2逆水煤气变换催化剂的研究 专业：化学工程与工艺 摘要 本论文主要是对介孔Ni-CeO2逆水煤气变换催化剂的研究。本文采用十六烷基三甲基溴化铵（CTAB）和P-123为表明活性剂，六水硝酸铈为铈源，六水硝酸镍为镍源，制备介孔Ni-CeO2催化剂。通过对介孔Ni-CeO2催化剂制备条件的改变，如温度、组分含量比例，不同表面活性剂等，采用微型反应炉及TPR,BET,XRD,孔径分布及等温吸脱附曲线来测试制得催化剂的活性和性能评价。 实验结果表明：①以CTAB为模板剂，1%镍含量的Ni-CeO2催化剂具有较高的活性和选择性。②以CTAB为模板剂，CTAB浓度与铈、镍浓度比为0.8时，所制得的介孔Ni-CeO2催化剂有较好的活性和选择性。③以P-123为模板剂，老化温度在80℃下所制得的介孔Ni-CeO2催化剂有较好的活性和选择性。④相比CTAB和P-123这两种模板剂，以CTAB为模板剂制备的介孔Ni-CeO2催化剂有较好反应活性，但选择性稍差，而P-123为模板剂制备的介孔Ni-CeO2催化剂有较好的选择性，反应活性稍差。 关键词：介孔材料；表面活性剂；活性；选择性 ABSTRACT This thesis is mesoporous Ni-CeO2 against the current gas shift catalysts .In this paper, cetyltrimethylammonium bromide (CTAB) and P-123 to show that the active agent, cerium nitrate hexahydrate as the cerium source, six nickel nitrate as nickel source of water to prepare mesoporous Ni-CeO2 catalyst. Through the mesoporous Ni-CeO2 catalyst preparation conditions, such as temperature, component content ratio, the different surface active agent, the use of micro-reactor and TPR, BET, XRD, pore size distribution and adsorption-desorption isotherms obtained curve to test the activity and performance evaluation. The results showed that: ① the CTAB as template, 1% nickel content Ni-CeO2 catalyst has high activity and selectivity.② The CTAB as template, CTAB concentration and cerium, nickel concentration ratio of 0.8, the prepared mesoporous Ni-CeO2 catalyst had good activity and selectivity.③ The P-123 as template, the aging temperature is 80 ℃, the prepared mesoporous Ni-CeO2 catalyst had good activity and selectivity.④ CTAB and P-123 compared to the two template to CTAB as a template to prepare mesoporous Ni-CeO2 catalyst has good reactivity, but somewhat less selective, while the P-123 as a template to prepare mesoporous Ni-CeO2 catalyst has good selectivity, reactivity somewhat less. Key words: mesoporous materials, surfactant, activity, selectivity 目录 中文摘要 I 英文摘要 II 1前言 1 1.1 引言 1 1.2 主题 1 1.2.1三效催化剂工作原理 1 1.2.2低温氧化催化剂 1 1.2.3、过渡金属氧化物低温氧化催化剂 2 1.2.4、CeO2