柴油机尿素SCR系统的钒基催化剂老化性能研究.pdfVIP

第 35卷 第 6期 内 燃 机 工 程 Vo1．35No．6 2014年 l2月 ChineseInterna1CombustionEngineEngineering Decem ber．2014 文章编号 ：1000--0925(2014)o6—0035—07 350113 柴油机尿素 SCR系统的钒基催化剂老化性能研究 刘 洋 。王家明。，孙 亮 ，白书战 ，李国祥 (1．山东大学 能源与动力工程学院，济南 250061； 2．无锡威孚力达催化净化器有限责任公司 技术研发 中心 ，无锡 214177) AgingTestonVanadium。BasedCatalystsEmployedin the UreaS‘CR System forDieselEngine LIU Yang ，WANG Jia—ming ，SUN Liang ，BAIShu—zhan～，LIGuo—xiang (1．SchoolofEnergyandPowerEngineering，ShandongUniversity，Jinan250061，China； 2．CenterofResearch andDepartment，W uxiW eifuLidaCatalyticConverterCo．，Ltd．，W uxi214177，China) ● Abstract：Agingtestsofhome—madeV205一WO3／TiO2catalystbasedonSCRtechnologywereconduc— tedrespectivelyonasteady—flow reactorandavehicledieselenginebench testtostudy theagingresistance performance，andthetestresultswerecomparedwithaforeigncommercialcatalyst．Meanwhile，character— izationanalysesofthetestedcatalystswerealsomadetobuildarelationshipbetweencatalystsstructureand ageingresistanceability．Theresultsofthecatalyticactivityexperimentsshow thathydrothermalaginghasa largenegativeeffecton thehome—madeand foreigncatalysts，whichresultin approximately 18 and15 reductionsofactivetemperaturewindow (NO conversionrate 60 )respectively．However，sulfuraging appearsonly3 activitylossonboth ofthecatalysts．Afterfastengineaging experiments，thehome—made andtheforeigncatalystsboth show NO conversiondeterioration，andtheformerismoreseverethan the latterinESC andETC testingcycles。butbothcatalystscanstillmaketheenginemeettheemissionlimitsof China-Ⅳ emissionsstandard．Theresultsofcomponentandstructureanalysesoncatalystsindicatethatthe majorreasonforcatalyticactivityreduc