一种黄心水泥熟料中的阿利特的微观的研究.pdfVIP

一种黄心水泥熟料中的阿利特的微观研究 张洪滔 陈益民 董刚 吴春丽 （中国建筑材料科学研究总院 绿色建筑材料国家重点实验室 建材行业水泥基材料科学重点实验室 北京 100024 ） 摘要：以扫描电镜与X 射线能谱仪研究黄心硅酸盐水泥熟料中阿利特的微观状态。结果表明：与正常黑色 熟料相对比，黄心熟料阿利特的中心部位铝、铁元素固溶量减少，影响其水化活性；阿利特边缘分解产物 为阿利特、贝利特、游离氧化钙等多种矿相，这些矿相中均含有较多量的铝、铁元素；黄心熟料中阿利特 附近的中间相存在铁元素的富集；铁元素在黄心熟料阿利特分解中发挥重要作用。 关键词：熟料 黄心 阿利特 微观 组成 中图分类号：TU528 Microcosmic Study of the Alite in a kind of Yellow Cement Clinker Zhang Hong-tao, Chen Yi-min, Dong Gang, Wu Chun-li （China Building Materials Academy, State Key Laboratory of Green Building Materials, Key Laboratory of Cement-based Materials Science, BeiJing, 100024 ） Abstract: By the scanning electron microscope and energy dispersive spectromrter, the microcosmic element composition of the alite in a kind of yellow cement clinker is discussed in this paper. The results showed as follows: (1) In contrast to those in the natural black cement clinker, the hydration activity of the alite in yellow cement clinker is not well. The reason is that the quantity of solid solubility of the ions of Fe and Al in center of the alite in yellow cement clinker is less than those of good cement clinker. (2)The yellow cement clinker witnessed that the edge of alite was decomposed to alite, belite and f-CaO. The quantity of the Fe and Al ions in them is more than those in normal mineral. (3) The yellow cement clinker witnessed the enrichment of Fe element happened in the matrix near alite. (4)The Fe is a important role in the decomposing process of alite. Key Words: cement clinker, yellow center, alite, microphenomenon, element composition 出现边棱不整齐，局部分解的现象，并将这 0 前言 种分解状态描述为阿利特的“花环”，其主 优质熟料是制备优质水泥的必要条 要分解产物为贝利特与二次游离氧化钙。X 件，水泥熟料是生料在水泥窑中经高温煅 衍射研究表明黄心熟料中并没有出现异种 烧、强行冷却后的产物。由于各种工艺原因， 矿物，熟料矿物组