水性聚氨酯_氧化石墨烯复合材料的研究_王乾乾.pdfVIP

33 卷第24 期 西 部 皮 革 Vol.33 No.24 西部皮革 第 33 卷 生 态 环 保 2011 年12 月 WESTLEATHER Dec.2011 水性聚氨酯/氧化石墨烯复合材料的研究 1* 1,2 王乾乾 ，王全杰 （1. 烟台大学化学化工学院，山东烟台264005 ；2. 国家制革技术研究与推广中心，山东烟台264003） 摘要： 采用改进的Hummers 法制备氧化石墨(GO)，超声剥离得到氧化石墨烯(GOs)。采用TEM 、FT-IR 和XRD 表征了形貌与结构，表明制备的GOs 剥离比较完全，稳定性较好。将GOs 与水性聚氨酯(WPU) 共混，正交试验法研究结果表明：GOs 的含量对WPU/GOs 复合材料耐水性的影响最大，而共混温度对 力学性能的影响最大。 关键词： 氧化石墨烯；水性聚氨酯；改性；正交试验法 中图分类号：TB 383-1 文献标识码：A 文章编号：1671-1602 （2011）24-0026-04 Research on Water-based Polyurethane/Graphene Oxide Composite Material WANG Qian-qian1*, WANG Quan-jie1,2 (1. College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, China; 2. State Research and Promotion Center of Leather Making Technology, Yantai 264003, China) Abstract: Graphite oxide(GO) was prepared by improved Hummers method, and then graphene oxide(GOs) was obtained via ultrasonic stripping. The morphology and structure of GOs were characterized by TEM, FT-IR and XRD. The results showed that the prepared almost completely tripped GOs had good stability. The waterborne polyurethane/grapheme oxide composite material was obtained by blending GOs with water-based polyurethane, and the results, obtained by the orthogonal test method, showed that the dosage of GOs had the greatest effect on the water resistance, but the blended temperature