聚酯微胶囊的研究及表征.pdfVIP

24 6 Æ Vol.24 No.6 2 0 1 0 12 CHINESE JOURNAL OF MATERIALS RESEARCH December 2 0 1 0 W/O/W/ ∗ (Æ 510640) W/O/W (XAMA–7)/, , : , 2 ; , 34.5 mJ/m2 ; 2.5% ; , 50%:50% , 22%; , , (XAMA–7) , XAMA–7 , , , , TB324 1005-3093(2010)06-0619-06 Synthesis and Characterization of Polyfunctional Aziridine/Polyester Microcapsules by W/O/W Multiple Emulsion–solvent Evaporation HU Jianqing∗∗ ZHENG Zhixian ZHU Haijun TU Weiping WANG Feng (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640) *Supported by National Natural Science Foundation of China No. and the Fundamental Research Funds for the Central Universities No.2009ZM0046. Manuscript received April 15, 2010; in revised form August 2, 2010. ** To whom correspondence should be addressed, Tel:(020 E–mail: glennhu@scut.edu.cn ABSTRACT A novel multiple emulsion–solvent evaporation method was successfully adopted to pre- pare polyfunctional aziridine/polyester cross linking microcapsules, during which various synthesis process parameters were discussed in detail. It was found that too fast a solvent evaporation rate would result in shrink porous microcapsules, and even hardening rate for microcapsule shell could be achieved with solvent evaporating in ca. 2 hours. Polyester with lower surface free energy was found to be beneficial for capsulation, and fully capsulated microcapsules were synthesized at 34.5 mJ/m2 . Adding 2.5% of colloid stabiliser could result in even–structured microcapsules with hollo