提高金属涂层和有机基材附着力的表面改性研究.pdfVIP

提高金属涂层与有机基材附着力的表面改性研究 霍纯青，桑利军，陈强*，岳蕾，付亚波 北京印刷学院印刷包装材料与技术北京市重点实验室，北京大兴，102600 摘要 利用等离子体技术在有机玻璃(亚克力版)上完成金属铝的膜层制备，进行了膜层表面 的光泽度、附着力和耐腐蚀性等研究。实验发现采用磁控溅射制备的金属Al膜的光泽度非常好， 镀层为镜面光洁。而为了提高耐腐蚀性，在金属膜上镀了一层硅薄膜，结果对Al膜的光泽度没有 影响。同时，根据国家标准，在配制10％的NaOH溶液中进行耐腐蚀性测试，结果表明铝膜表面 没有任何被腐蚀的现象产生，薄膜耐腐蚀性能良好。但是金属薄膜在有机基材上的附着力较差， 为此进行了利用Ar 、O2等离子体对有机玻璃表面进行清洗，其目的一是对表面进行清洗，以除去 其表面附着的杂质污染物；其次等离子体轰击使表面变得更粗糙，有利于提高其对金属膜的附着 力；此外在薄膜表面添加过渡层，即在镀膜之前先在基材上镀一层其他材料，然后再镀金属膜。 实验发现环氧材料和SiO2作为过渡层，薄膜的附着力显著提高。 关键词 等离子体应用；磁控溅射；附着力 The study of adhesive between Al layer on PMMA surface by plasma treatment ABSTRACT: Using magnetron sputtering reactor technology metal coatings such as Al was deposited on the surface of PMMA. In this process, we have explored the brightness, anti-corrosion and adhesion of the Al coatings. It is found that the film is very brightness as a mirror. The nano-scale deposited silicon oxide layer on Al surface for anti-corrosion propose did not decay the brightness. The anti-corrosion experiment, by the national standard of immersion in 10% NaOH solution for 1min, demonstrated no corrosive phenomena. However, the adhesion between metal coating and PMMA is relatively small. So lots of works were done for this propose. Firstly, we used Ar and O2 plasma to clean PMMA surface, in which plasma can clean and remove the impurity from the surface besides the roughness by the radical bombardment. Then we coated a transition layer on the surface before deposition the metal. We found that transition layer of epoxy and SiO2 can improve the adhesion notably. At the same time, there is still one problem we should pay attention the transition layer may affect the coating brightness and endure ability. 1.前言 有机玻璃化学名为聚甲基丙烯酸酯（PMMA ），由于它具有良好的电绝缘性能、化学稳定性