生物质成型燃料热解焦油性能和成分研究.pdfVIP

生物质成型燃料热解焦油性能及成分研究 刘石彩，边 轶，简相坤 ( 中国林业科学研究院 林产化学工业研究所；生物质化学利用国家工程实验室； 国家林业局 林产化学工程重点开发实验室，江苏南京 210042) 摘要：通过与煤焦油性能对比分析，发现白松木成型燃料热解焦油的含水量较高，氧元素含量高，N 、S 含量很 低，热值很低，成型燃料热解焦油的酸值较高，具有较强的腐蚀性。采用傅里叶变换红外光谱仪对松木焦油进行 官能团结构分析知其含有-OH、-C=O 以及芳香族基团。对不同气氛下焦油的热重分析表明，常温下焦油的保存期 长短对其化学组成影响很小。在两种情形下 300℃以下焦油的热重曲线基本吻合，且焦油在 150℃左右热解速率 开始加快，而后在空气气氛下400 ℃左右焦油热解多出了一个燃烧阶段，且残余量很小。利用用色谱-质谱联用技 术分析出热解焦油的41 种主要成分，总相对百分比含量为79.25%，其中相对含量较高的是3-羟基-4- 甲氧基甲苯 （9.79% ）、4-乙基愈创木酚（8.43%）、愈创木酚（6.83% ）等。 关键词：成型燃料；焦油；红外；热重分析；气-质联用色谱 Properties and Chemical Component of Pyrolysis Tar of White Pine Molding Fuel LIU Shicai, BIAN Yi, JIAN Xiangkun (Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. on Forest Chemical Engineering, SFA, Nanjing, 210042, China) Abstract ：The pyrolysis tar of white pine molding fuel was detected having the high content of water and oxygen，while having the low content of nitrogen and sulfur. The tar was strong corrosive for its high acid value. Carbonyl, hydroxyl and aromatic groups were detected in tar by infrared spectral. TGA were studied in different atmosphere ，the result indicated that thermogravimetric curve of tar was basic accordance under temperature 300 ℃. Meanwhile it was more than a burning stage in air atmosphere compared with nitrogen atmosphere of the tar. Forty-one compounds were separated and identified from pyrolysis tar by GC-MS analysis ，these compounds were account for 79.25 % of total tar ，Among the main components, the relative content of 3-hydroxy -4-methoxytoluene was highest to 9.79 %, 4-ethylguaiacol up to 8.43 % and guaiacol up to 6.83 %. Keywords: molding fuel, ta