4-点阵常数测量-课件-姜锋.pdfVIP

X 2θ2dsinθ=λabc d -5 -4 10 nm 10 Å -5 -6 ±10 nm±10 nm hkld 2θ -4 X 10 Å θsinθ=λ/2dλ λ ∆d cos d sin θ∆θ − ∆ − θ 2d2 d ∆d cot − θ∆θ d d / d a / a ∆ ∆ ∆a cot − θ∆θ a ∆θ ∆a/acotθ θ→90°∆a/a→0 θ=90° θ90° ∆θ=1θd θ 30 50 70 75 80 85 ∆d/d% 0.050 0.024 0.011 0.008 0.005 0.0025 10°2θ 22θ/θ2:1 3 4 5 1