氯化银%2f聚甲基丙烯酸甲酯有机－无机杂化膜地研究.pdfVIP

1.3 传质与分离工程 氯化银/聚甲基丙烯酸甲酯有机－无机杂化膜的研究 1 2* 2 1 2 郑幸存 ， 吴礼光 ，汪锰 ，裘俊红 ，高从堦 1.浙江工业大学化材学院，杭州，310014 ； 2. 国家液体分离膜工程技术研究中心，杭州，310012 摘要：以甲基丙烯酸甲酯（MMA ）为油相，利用微乳液聚合技术制备了氯化银/聚甲基丙烯酸甲酯（PMMA ） 有机－无机杂化膜。扫描电镜分析了膜的结构，结果表明微乳液聚合后形成了以氯化银为核，聚甲基丙烯 酸甲酯为壳的核－壳型无机－有机杂化膜材料；氯化银微粒在聚甲基丙烯酸甲酯中均匀分散，形状规则， 粒径大小均在2 μm 以下。环己烷、环己烯在氯化银/聚甲基丙烯酸甲酯无机－有机杂化膜中的溶胀吸附性 能研究结果表明，与聚甲基丙烯酸甲酯膜相比，环己烯在杂化膜中的溶胀吸附性能显著提高，而环己烷的 溶胀吸附性能却相差不大。 关键词：促进传递；有机－无机杂化膜；溶胀吸附；环己烷；环己烯 Study on AgCl/PMMA Organic –Inorganic Hybrid Membrane 1 2* 2 1 2 Zheng Xingcun , Wu Liguang , Wang meng , Qiu Junhong , Gao Congjie (1. Zhejiang University of Technology, Hangzhou 310014 2. National Engineering Research Center for Liquid Separation Membrane, Hangzhou 310012) Abstract: AgCl//PMMA organic-inorganic hybrid membrane has been fabricated by reverse microemulsion polymerization using methyl methacrylate (MMA) as oil phase.The membrane structure is analyzed by scanning electron microscope(SEM), which shows that core-shell organic-inorganic hybrid materials are formed with AgCl as the core and PMMA as the shell. AgCl particulate under 2 μm are uniformly dispersed in the PMMA. The swelling-sorption behavior of the cyclohexane and cyclohexene in AgCl//PMMA hybrid membrane are measured ,and the result indicates that the sorption capacity of cyclohexene in the hybrid membrane is enlarged comparing with pure PMMA membrane, but the sorption behavior of cyclohexane is less changed. Keywords: facilitated transport ; organic-inorganic hybrid membrane; swelling-sorption behavior; cyclohexane; cyclohexene 引言 + 2+ 金属离子Ag 、Co 等能与烯烃、芳烃等有机物形成电子给体－受体络合物。利