陶瓷膜分离油中含水乳液的研究.pdfVIP

陶瓷膜分离油中含水乳液的研究* 李梅，高能文，范益群 (南京工业大学化学化工学院，材料化学工程国家重点实验室，江苏 南京210009) 摘 要：本文对平均孔径50 nm 、表面疏水改性的陶瓷膜分离油中含水乳液进行了研究。考察了跨膜压差、 膜面流速、原料液水含量对膜渗透通量及水截留率的影响。结果表明，采用疏水改性陶瓷膜分离异辛烷中 含水乳液可得到较高通量，且水截留率均在98% 以上。增大跨膜压差或减小原料液水含量可以增加膜稳定 通量；而随着膜面流速的增加，膜稳定通量先升后降；渗透侧水含量不随操作条件的改变而改变。实验得 出，适宜的操作参数为跨膜压差0.1 MPa、膜面流速1.67 m/s 。 关键词：油中含水乳液；陶瓷膜；疏水改性；膜分离 Separation of water in oil emulsions using ceramic membranes Li Mei, Gao Nengwen, Fan Yiqun (College of Chemistry and Chemical Engineering, Nanjing University of Technology, State Key Laboratory of Materials -Oriented Chemical Engineering, Nanjing 210009) Abstract :Hydrophobic ceramic membranes with the average pore size of 50 nm were employed to separate water -in-oil emulsions, in which isooctane and distilled water were selected as continuous and dispersed phase, respectively. The effects of transmembrane pressure, crossflow velocity and feed water content on permeate flux and water rejection were investigated. The results indicated that, the permeate flux of the modified ceramic membrane first declined with time and then kept constant while the water rejection was stable and as high as more than 98% all the time. Either increasing the transmembrane pressure or decreasing the feed water content could improve the permeate flux, and with the increase of crossflow velocity, the permeate flux initially raised and then decreased. The optimal operating conditions were transmembrane pressure of 0.1 MPa and crossflow velocity of 1.67 m/s. However, it was found that, the water content in the permeate kept constant in all operating conditions, owing to the hydrophobic surface of the modified ceramic membrane. Key words: water-in-oil emulsions; ceramic membrane; hydrophobic modification ；membrane separation 引 言