高能球磨法制备片状银粉的研究.pdfVIP

* I38 高能球磨法制备片状银粉的研究 1,2,3 1,2,3 1,2,3 1,2,3 1,2,3 1,2,3 1,2,3 张磊 ，甘国友 ，严继康 ，杜景红 ，易健宏 ，伍权 ，郑娅 , 陈忠文1,2,3 （1.昆明理工大学材料科学与工程学院;2.稀贵及有色金属先进材料教育部重点实验室;3.云南省新材料制备与 加工重点实验室，云南，昆明 650093 ） 摘要：采用高能球磨法制备了片状银粉。利用正交实验法、激光粒度分析仪、扫描电子显微镜，研究了银粉在高能球磨过 程中，片状银粉粒径和形貌随球磨工艺的变化情况。讨论了球磨时间、分散剂、球磨转速、球料比对片状银粉的粒度、形貌、团 聚、比表面积、片状化程度等性能的影响。研究结果表明：采用无水乙醇为球磨助剂，硬脂酸钙为分散剂，球磨时间 20h ，球磨 转速 250r/min，可制得粒径达到 8.55μm、比表面积为 0.67m2/g 、片状化程度高、团聚少的超细片状银粉。 关键词：片状银粉 高能球磨 正交实验法 分散剂 Preparation of Flake Silver Powder by High Energy Ball Milling ZHANG Lei1,2,3,GAN Guoyou1,2,3,Yan Jikang1,2,3,Du Jinghong1,2,3,YI Jianhong1,2,3,WU Quan1,2,3,ZHENG Ya1,2,3,Chen Zhongwen1,2,3 (1.Faculty of Materials Science and Engineering Kunming University of Science and Technology, 2.Key lab. Of advance Materials in RarePrecious and Nonferrous Metals, 3.Ministry of Education,P.R china key lab. Of Advance Materials of Yunnan Province, Kunming 650093) Abstract: Flake silver powder was prepared by high energy ball milling. During the high energy ball milling process, the conversion of silver powder was researched by the orthogonal experiment method, the laser particle analyzer, the scanning electronic microscope and energy disperse spectroscopy. The influences of the milling time, the dispersing agent, milling speed and ratio of ball to powder on the distribution of particle size and the particle shape were studied. The results show that the less agglomerated ultrafine flake silver can be obtained by milling for 20h when using ethanol as grinding aids, calcium stearate as dispersing agent. The flake silver has better properties with an average particle size of 8.55 μm, specific surface are