皂角苷增强洗脱复合污染土壤中多环芳烃和重金属的作用及机理.pdfVIP

农业环境科学学报2010，29(12)：2325—2329 of Science Journal Agro-Environment 皂角苷增强洗脱复合污染土壤中多环芳烃和 重金属的作用及机理 陈 洁1，杨娟娟2周文军2-3 室。杭州310028) 脱作用及机理。结果表明，皂角苷对菲、芘等多环芳烃有极强的增溶作用，当皂角苷浓度为0．04％时，菲、芘在液相中的表观溶解度 增大了约2倍和17倍。皂角苷可与重金属离子形成水溶性的络合物．从而增强洗脱重金属污染土壤中的zn“和c驴，在皂角苷浓度 脱效率，但多环芳烃对zn“、cd2+的洗脱效率没有明显影响。皂角苷可同时增强洗脱复合污染土壤中的多环芳烃和重金属，从而为多 环芳烃一重金属复合污染土壤的修复奠定基础。 关键词：生物表面活性剂；皂角苷；多环芳烃；蕈金属；复合污染土壤；增强洗脱 中图分类号：X53 文献标志码：A 文章编号：1672—2043(2010)12—2325-05 SimultaneousRemovalof Aromatic and Metalfrom Soils Polycyclic HydrocarbonsHeavy Plant—Derived bySaponin．a Biosurfactant CHENJiel。YANG Juan-ju彻2ZHOUWen-junz3 ofEnvironmental (1．DeqingEnvironmentalMonitoringStationofZhejiangProvince，Deqing313200，China；2．Department Provincial of PollutionProces8and 310028， University，Hangzhou310028，China；3．ZhejiangKeyLaboratoryOrganic Control。Hangzhou China) Abstract：Biosurfaetantshave intheremediationof contaminatedsoils鹏theirenvironmentalnature．The greatadvantages organic friendly removalof fromCO— of the aromatic metal performancesaponin，aplant-derivedbiosurfactant，forpolycyclichyclrocathons(PAHs)andheavy werestudied．neresults Can enhancethesolubilizationof and in80-- contaminatedsoils indicatedthat saponingreatly phenanthrenepyrene the oftheminto mlcelleandthentheremov,alof and fromPAHs--contaminatedsoil．弧emax— htion by partition saponin phenanthrenepyrene imumremovalratesof84．1％and81．4％wereobtainedfor and fromPAHs-contaminated