空间探索力原子反应英语.ppt

Preparation of Carbon-encapsulated Fe core-shell nanostructures by Confined arc plasma Zhi-qiang Wei, Xiaoyun Wang,Hua Yang State Key Lab. Of Gansu Advanced New Non-ferrous Metal Materials Lanzhou University of Science Technology Outline 1. Introduction 2. Experimental 3.Results and discussions 4. Conclusions Introduction During the past years, metal nanoparticles have attracted considerable attention due to their novel physical and chemical properties. However, the naked metal nanoparticles are unstable, and the practical applications of such nanoparticles are limited due to the sensitivity to air oxidation. Carbon encapsulated metal nanoparticle have attracted increasing attention compare with the naked metal nanoparticles,not only because they could retain their proper nanocrystalline properties, but also they offer an opportunity to investigate dimensionally confined systems. Arc discharge technique is one of the conventional techniques for fullerenes and carbon nanotubes synthesis, which provides a convenient and simple platform for fabrication of carbon encapsulated metal nanoparticles. But the synthesis system and processes are expensive and complicated, and limited by the lack of scalable production technique for mass production,etc. Therefore, the conventional arc discharge techniques need be improved. experimental equipment experimental procedure In the process of preparation, the synthesis chamber was evacuated to 10-3 Pa and dilute twice by Ar, then fill Ar to a wanted pressure; The arc is automatically ignited by the high frequency ignited device; The bulk metal Fe is melted by the high temperature of the plasma; The vaporization of Fe and gasification of carbon occurred concurrently; Later , the droplets are rapidly cooled and combined to form primary particles;carbon encapsulated Fe nanoparticles are formed . At last, The particles are transported from the