CO3^2-和C12H25SO4^-在MgAl双氢氧化物层间通道中的竞争嵌入的机制研究.pdfVIP

第 32卷 第 2期 周 口师范学院学报 2015年 3月 VoI．32No．2 JournalofZhoukouNormalUniversity Mar．2015 Acompetitionmechanism betweenCo；andC12H25SOl intheinterlayergalleryofMg／AIlayereddoublehydroxides LIHaojie，WU Dingwei，JIA Xinliang，I．IBiao·CHENMia。，WANG I．inhong．LIU Xiaoiuan， JIA ChunII【1g，PENGPeng* CollegeofChemistryandChemicalEngineering，ZhoukouNormalUniversity， Zhoukol1466001，China Abstract：SitecompetitionamongC0 andCf?H25S DS intheinterlayergalleryofMg／A1一layereddouh lehydroxides LDHs isdeterminedthroughaseriesofexperimentsandthecompetitionmechanism ispro posed．LDH ～DScarlbeeffectivelysynthesizedandmeetstherequirementsofexperimentqualitythrough l spontaneousself—assemblymethod．ThesamplesarecharacterizedbyX —raydiffraction XRD ， C，H ，and N elementalanalysis，FTIR spectra ． C ； ionshaveaverystrongaffinitytoLDHs，whichinevitablvaffect thesynthesisofLDH—DS．However，anionsC ； andCl2H25S cannotcombine1ayerstogetherintheI1一 terIayergallery，becauseofbiggapinthespacingoflayersbetweenLDH —DSandLDH —CO ． Keywords：intercalationreaction~interlayergallery；layereddoublehydroxides CLCnumber：O 175．9 Documentcode：A ArticleID：1671—9476 2015 02—0074—05 DOI：10．13450／j．cnki．jzknu．2O15．02．021 Intercalation of organic guest species into Thepopulardelaminationmethod isinterca— layeredinorganicsolidsisawayofproducing or— lationoforganicguestmoleculeintotheinterlay deredinorganic—organicassemblieswith unique ergallery，whichalsoisamoredirectandsimple microstructurescontrolled by host— guestand method． Generally， sodium dodecyl sulfate guest～ guest interactions [一 ． Among possible NaDS is chosen astheguestorgallery anion layeredmaterials。compoundsin theanion—ex— [一 ， which isalong surfactantanion and leads changegroup are relatively rare．Iayered double delam ination ofLDHsby a convenientphysical hydroxides LDHs areaclassoflayeredmateri— method．Itisknown thatC ionshaveavery alsconsistingofpositively chargedbrucite—like strong affinity to LDHs ． According to the layers and the interla