石灰石粉对水泥早期与后期强度贡献的差异.pdfVIP

第十二届全国青年材料科学技术研讨会（2009年11 月27-30） 6 绿色建筑与生态环境材料 石灰石粉对水泥早期和后期强度贡献的差异 文俊强，张文生，张建波 （中国建筑材料科学研究总院，绿色建筑材料国家重点实验室，北京 100024 ） 摘 要：石灰石粉掺和料在水泥浆体硬化的不同时期表现为不同的强度贡献，研究其强度贡献的差异对于合理 利用石灰石粉资源有十分重大的意义。本文通过微量热仪测量水泥浆体的早期水化放热和XRD 衍射分析仪分析 水泥浆体水化产物研究了石灰石粉对水泥硬化浆体早期强度的影响，用扫描电镜观察水泥硬化浆体微观结构的 变化研究了石灰石粉对水泥硬化浆体后期强度影响。试验结果表明：石灰石中部分细小微颗粒可以充当水泥水 化的晶核，形成晶核效应，加速水泥水化，从而对水泥早期强度产生正贡献；由于石灰石粉本身颗粒具有方解 石的形貌，方形碎块的表面整齐光滑，因此石灰石粉掺入水泥中在石灰石粉颗粒与水泥水化产物的界面容易形 成平整断面，对水泥后期强度产生负贡献。 关键词：水泥；石灰石粉；强度贡献；微量热仪 The difference strength of limestone contribute to cement at early age and later age WEN Junqiang ，ZHANG Wensheng ，ZHANG Jianbo ( China building material academy, State key laboratory of green building material, Beijing 100024) Abstract ：There is the difference strength of the limestone filler contribute to cement at difference hydration age, understanding the contribution difference will be helpful to reasonably utilize the limestone resource. This paper studies the cement with limestone hydration heat by the TAM air isothermal calorimeter and the new hydration compound by the X-ray diffraction at the early age; the harden cement paste investigates the using the scanning electron microscopy in order to explain the reason of cement with limestone strength reduce at the later age. The experiments show that micro-sized CaCO3 grain nucleate in the cement paste, accelerate the cement hydration, so the strength of limestone contribute to cement is positive at early age. The limestone is composed of many calcite which is lubricity crystal, the surface of crystal is easy to form the rupture in cement paste, so the strength of limestone contribute to cement is negative at later age. Key words：cement strength; limestone; strength contribution; micro-calorimetry instrument 0 引言 石灰石粉作为一种新的掺合料越来越多的应用于水泥混凝土