含单宁废液的生物降解特性研究.pdf

第4卷 第9期 2009 年 9 月 中国科技论文在线 Sciencepaper Online 1 含单宁废液的生物降解特性研究 1 2 1 1 何贵萍 ，申 琳 ，马 佳 ，何 强 （1.四川大学轻纺与食品工程学院, 成都 610065 ；2. 中国农业大学食品科学与营养工程学院, 北京 100083 ） 摘 要：本文基于废液的污染负荷、生化呼吸和降解动力学等特性，以制革铬鞣工艺为对照，对植鞣工艺所排放废液 （含单宁废液）的生物降解特性进行了研究。结果表明，由于铬和单宁对活性污泥的抑制，来自于铬鞣和植鞣工艺的 废液的生物降解性能都较差，其BOD5/COD值分别为 10.7%和 23.6% ，生化处理 14 d后其降解率分别为 18.0%和 34.7%。 动力学研究结果表明，稀释处理不能改善铬鞣废液的可生化性，但可以显著提高含单宁废液的生物降解性能。1:9 (v:v) 稀释后，活性污泥能迅速高效地降解来自于植鞣工艺的废液（单宁浓度 490 mg/L ），其可生物降解程度达49.5% 。 关键词：皮革；植鞣；铬鞣；单宁；废液；可生物降解性 中图分类号：TS 57 文献标识码：A 文章编号：1673－7180(2009)09 －0000 －0 A study on the biodegradability of tannin-containing wastewater 1 2 1 1 HE Guiping ，SHEN Lin ，MA Jia ，HE Qiang (1. College of Light Industry and Food Engineering, Sichuan University, Chengdu 610065, China; 2. College of Food Science Nutritional Engineering, China Agricultural University, Beijing 100083, China) Abstract: The biodegradability of wastewaters collected from traditional vegetable-tanning (VET) and chrome-tanning (CRT) processes in leather industry has been investigated by studying on the pollutant loads, the respiration of activated sludge and the degrading kinetics. Both CRT and VET wastewaters showed low biodegradability due to the presence of chrome or tannin, which the BOD5/COD values were 10.7% and 23.6%, and the biodegradation ratios were 18.0% and 34.7% , respectively after 14 days of activated sludge treatment. Kinetics study indicates that dilution treatment has no substantial effect on the biodegradability of CRT wastewater, but it can largely imp