COD测定方法的发展与研究动态_唐圣钧.pdfVIP

— 40 — 2005 24 1 · · COD 唐圣钧, 石　磊, 赵由才 (, 　200092) 　　:本文较为全面地论述了COD 测定方法的发展与研究现状。在论述了 标中COD 标准方法不足之处的基础上, 本文就标 准方法的众多改进措施分类进行了比较与探讨, 包括消解方法的改进、 替代催化剂的研究以及氯离子干扰的消除, 然后介绍 了相关系数法、 电化学法、 分光光度法和流动注射法等COD 测定替代技术。本文认为, 研究试剂用量少、 无污染的绿色COD 测定方法具有重要而积极的意义, 而研究适应性强、 运行可靠、 性价比高的COD 在线监测仪则是COD 监测的发展趋势。 　　: (COD);;;; :X830.2 　　　　:A　　　　:1001-3644 (2005)01-0040-04 Research Progress of COD Determination Methods TANG Sheng-jun, SHI Lei, ZHAO You-ai (S tate Key Laboratory of P ollution Con trol and R esource R euse, Tongj i Un iversity , S hanghai 200092, China) Abstract:This paper summarizes the resear h progress of COD determination methods overall at present.Based on the short omings of the COD determination method revised in National Standard, some improvement measures of the standard method, in luding improvement of slaking phrases, resear h of substitution ataly sts and elimination of hlorine ion disturban e, are ompared and dis ussed.Afterwards, some alternative methods, su h as orrelation oeffi ient analysis method, ele tro hemi al analysis method, spe trophotometri analysis method, and flow inje t analy sis method, are introdu ed.At last, the authors point out the developing trend of COD determination method, a green COD determination method with less reagent onsumption and no pollution, and the developing trend of COD monitoring, COD online monitoring instrument w ith wide adaptability and high performan e-pri e ratio. Key words:COD;determination method;improvement;resear h progress;green 1　引　言 , 、 、 COD 。, , COD COD , 。 COD , , ,