氢化丁腈橡胶的结构与性能研究.pdfVIP

　 31 Molecular Structure and Properties of Hydrogenated Nitrile Rubber , 　, , (, 100095) ZHANG Ju- ua, WANG Z en, ZHANG Hong-yan, SU Z eng-tao (Beijing Institute of Aeronautical M aterials, Beijing 100095, C ina) :(IR)、 (DSC), (T GA )(H NBR) 、。 , H NBR 720 ～ 730cm-1 (CH )(n 4) 2 n , HNBR (NBR);, H NBR ; , , , H NBR 。 :;;;; :T Q333.7 　　:A 　　:1001-4381(2011)02-0031-04 Abstract:A relations ip of molecular structure and p ysical properties at low and ig temperatures of ydrogenated nitrile rubber (HNBR)w as investigated by Infrared (IR)Spectroscopy, Differential Scanning Caloricity (DSC )and T ermo Gravimetric Analysis (TGA ).It is s ow n t at HNBR as c aracteristic peak of t e (CH2 )n (n 4)in t e backbone at 720-730cm-1 for identified HNBR from NBR.T e initial decomposition temperature rose w it t e increase of t e acrylonitrile content and y- drogenation .It is also concluded t at t e ig er acrylonitrile content, t e ig er Tg , tensile strengt and compression set of HNBR, w ic could be attributed to t e crystallization caused by more content of repeat units. Key words:ydrogenated nitrile rubber;molecular structure;low temperature property; ig temper- ature property;mec anical performance 　　(HNBR)(NBR) );(TAIC), ;1, 4- 。 HN- (BIPB), ; BR , 。 、; 1　 HNBR NBR Table 1　Raw materials , Acryl