阳离子型涂料印花用增稠剂的制备及其性能研究.pdfVIP

39 12 Vol. 39 No. 12 2009 12 PA INT COAT INGS INDUSTRY Dec. 2009 曹 原, 秦培勇 , 胡 彦 ( 北京化工大学生命科学与技术学院, 北京 100029) : , N, Nc- , - - , ( AM )( MAPTAC ), , , : 3% 47 Pa# s, 0105% 3219% , 231 6% , 1 m in : ; ; ; ; : TQ 63014 : A : 0253- 4312( 2009) 11- 0066- 04 Study on Preparation and Properties of Cationic Thickeners for Pigm ent Printing Cao Yuan, Q in Pei ong, H u Y an (College of Lfie Science and Technology, B eij ing University of Chem ical Technology, Beij ing 100029, China) Abstract: The title cation ic th ickenerw as prepared b reversed phase emulsion copol merizationw ith ac- r lam ide and 2- propenam ide( 3 - methacr lam id prop l) trmi eth lammon ium ch loride as monomers, N, N c meth lene- b is- ( acr lam ide) as crosslinker, cumene h droperox ide- sodium bisulfite as initiator, w h ich show ed good th icken ing effect, salt tolerance and eas app lication. The sign ificant factors for the th ickener w as determ ined b orthogonal expermi ent and range anal sis. The best pol merization condition w as con- firmed b single factor anal sis. The results show ed that the appearant viscosit ofw hite coatings contain ing 3% of th ickener(w /w ) reached up to 47 Pa# s and the rate of reserved viscosit in 0105% sodium ch lor ide aqueous solutionw as 3219%, the viscosit index w as 2316% and it onl need 1 m in to ach ieve the best th ickning effec.t K ey Words: reversed phase emu lsion polm erization; cationic monomer; orthogonal expermi ent; salt tol- erance; viscosit index 0 (MAPTAC), ,