工业双戊烯催化脱氢制备对伞花烃放大试验统计英文.pdfVIP

第 45 卷第 2 期 生 物 质 化 学 工 程 Vol． 45 No． 2 2011 年 3 月 Biomass Chemical Engineering Mar． 2011 · ——— · 研究报告 生物质化学品 Pilot Experimental Statistics for Preparation of p -Cymene from Industrial Dipentene by Catalytic Dehydrogenation BI Liang-wu ，ZHANG Qiu-ge ，ZHAO Zhen-dong ，LI Da-wei ， LI Dong-mei ，GU Yan ，WANG Jing ，CHEN Yu-xiang ，LIU Xian-zhang ( Institute of Chemical Industry of Forest Products ，CAF; National Engineering Lab． for Biomass Chemical Utilization; Key and Open Lab． on Forest Chemical Engineering ，SFA; Key Lab． of Biomass Energy and Material ，Jiangsu Province ，Nanjing 210042 ，China) Abstract: A 20 t / a scale pilot experimental device for continuous gas-phase catalytic dehydrogenation of industrial dipentene was designed and tested． The catalytic dehydrogenation could be continuously carried out under the conditions of temperature 280－300 ℃ ，nitrogen flow rate 2 ． 0 L / min ，industrial dipentene flow rate 4 ． 0 L / h． The average mass ratio of industrial dipen- tene to crude product ( kg / kg) was 1． 11． The crude product of dehydrogenation was easily purified by the vacuum rectification apparatus． Mass ratio of industrial dipentene to p -cymene product ( kg / kg) was 1． 81 ( purity over 99 ． 0 % ) ，1． 69 ( purity over 98． 0 % ) ，1． 54 ( purity over 96． 0 % ) and 1． 45 ( purity over 90 ． 0 % ) ，respectively． The boiling point ，relative density and refractive index of p -cymene product with 99 ． 5 % purity were 177 ． 1 ℃ ，0 ． 857 g / mL and 1． 490 ，respectively． The pilot experi- mental statistics could provide services for engineering or industrialization development of p -cymene manufacture from industrial dipentene． Key wor