从蛇纹石制取碱式碳酸镁工艺探究.pdfVIP

从蛇纹石制取碱式碳酸镁工艺研究 1 1 2 1,2 崔静磊 ，郑曌 ，雷永汉 ，董声雄 1 2 ( 福州大学化学化工学院，福建 福州 350108 ； 宁德师范学院化学系，福建 宁德352100) 4 摘要：研究了以蛇纹石为原料制取碱式碳酸镁的工艺。通过 L16(4 )正交试验法对酸浸过程进行研究，结果 表明：在浸取温度100℃、浸取时间4h 、硫酸浓度40% 、液固比为4 时，镁的浸取率达到98.16% 。考察了 以氨水和碳酸氢铵为沉淀剂制取碱式碳酸镁的工艺条件，最佳工艺条件为：预氨pH 值为9.6~9.7、反应温 度为40oC、镁离子与总铵（NH +NH + ）摩尔比为0.46、氨与碳酸氢铵摩尔比为1.4。在最佳工艺条件下， 3 4 镁的沉淀率达到最大值89%。 关键词：蛇纹石；碱式碳酸镁；酸浸；氨水；碳酸氢铵 中图分类号：TQ 028.8 文献标识码：A Study on technology of producing basic magnesium carbonate from serpentine 1 1 2 1,2 Cui Jinglei , ZhengZhao ，Lei YongHan ，Dong Shengxiong 1 ( College of chemicalchemical engineering, Fuzhou University ，Fuzhou 350108, Fujian,China; 2Department of chemistry, Ningde Normal University, Ningde 352100, Fujian, China) Abstrat: Technology of producing basic magnesium carbonate from serpentine has been studied. 4 The leaching process of serpentine in sulfuric acid was studied through orthogonal L16(4 ) experiments. The results indicated that, when the leaching tempreture was 100℃, the leaching time 4h, the concentration of sulfuric acid 40%, the leaching ratio of magnesium in serpentine was up to 98.16%. Technological parameters of producing basic magnesium carbonate with ammonia and ammonium bicarbonate as precipitating reagent were investigated. The results showed that the optimal technological parameters were: aminated pH value was 9.6~9.7, reaction temperature 40 ℃, mol-