Fe3%2b%2fN-TiO2填料日光催化处理微污染水源水中试研究.pdfVIP

Fe3+/N-TiO 填料日光催化处理微污染水源水的中试研究 2 刘佳玉 ,张玉先,杜尔登,赵绪兰( 同济大学 污染控制与资源化研究国家重点实验室,上海 200092) 摘要:采用溶胶-凝胶法制备了铁、氮共掺杂二氧化钛(Fe3+/N- TiO )粉末.通过浸渍涂膜法将其负载到聚丙烯(PP)生物填料上,研究中试规模 2 3 下, 日光激发改性TiO 对微污染水源水的处理效果.结果表明,铁、氮的掺杂大大提高了TiO 对太阳光的利用效率, 当流量为0.12m /h 时,负载 2 2 型 Fe3+/N-TiO 填料对COD 和NH -N 降解率分别达到59%和65%.扫描电镜观察运行前后填料的表面状况,发现Fe3+/N-TiO 膜保持程度较 2 Mn 4 2 好,运行3个月后未发生明显脱落.膜表面生长了类似微生物的物质,可以推测,在PP填料表面微生物与二氧化钛形成了功能分区,可以同时进 行光化学氧化和生物降解作用. 关键字:太阳光 光催化 二氧化钛 中试 微污染水源水 中图分类号: 文献标识码:A 文章编号: A pilot scale investigation of micro-polluted source water treatment by solar immobilized Fe 3+/N-TiO2 LIU Jia-yu, ZHANG Yu -xian, DU er-deng, ZHAO Xu-lan (Tongji University, The National Key Lab. of Pollution control and Resource Research, Shanghai 200092,China) Abstract:Fe3+/N-doped Titania nanopowder was prepared by sol-gel method and coated by dipping method on the polypropylene bio-stuffing. This modified immobilized titanium dioxide was tested in the treatment of micro-polluted source water by solar photocatalysis at a pilot scale. The results showed that the titanium dioxide doped by Fe3+/N 3 obtained a higher efficiency in use of solar, and when the amount of flows is 0.116m /h, the degration rates of CODMn and NH -N achieved 59% and 65% respectively. The surface of the stuffing was characterized by ESEM before and after 4 working for