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Preparation of Mesoporous Ce0.5Zr0.5O2 Mixed Oxide by Hydrothermal Templating Method.pdf
维普资讯
Availableonlineat1^n^n^r.sciencedirect.com
掣 JOuRNALOF
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盼 ScienceDirect 衄 脚 ⅡS
JOURNALOFRAREEARTHS25(2oo7)710—714 WWW.elsevier.c0m1/0~ re
PreparationofM esoporousCe05Zr0502M ixedOxideby
HydrothermalTemplatingM ethod
GuYingying(古映莹) ,FengShengsheng(冯圣生),LiJinlin(李金林),GuXiangkui(顾向奎),
WangManjuan(王曼娟)
n CollegeofChemistryandChemicalEngineeringCentralSouthUniversity Chnagsha410083.Chnia,2.Key
LabDrcUDry ofCatalysisnadMcUenalsScienceoftheStateEthnicAffairsCommission&MinistryofEduction,
HubeiProvince,South.CentralUniversityfo,.Nationalities,Wuhna 430074,China)
Received20M arch2007;revisde 7June2007
Abstract:M esoporousCe05Zr0sO2mixedoxidewithhigh specificsurfaceareawassynthesizedunderbasicconditionin
thepresenceofnon—ionicsurfactantPEG-4000.Theeffectofsynthesisconditions,suchas synthesistemperatureandthe
mo ratioofPEG-4000/([Ce]+[Zr]),onspecificsurfaceareawreeinvestigated.Theproductswreechraactrezideby
trnasmissionelectronmicroscopy,powdre X—ray diffraction,na dnitrogenadsorption—desorptionmeasuremnets,respec—
tively.TheresuItsshowde thatsynthesistemperaturenadthemolarratioofPEG-4000/(1CeJ+lZrJ)had greatinflu—
enceOn specificsurfaceraae .Undre theoptimum synthesisocnditions,theprepraedCe05Zroj02mixde oxidepresnetde
cubicfluorite—typestructurenadpossessde hihg surfaceraae of148.6m ‘g withwormlikepores·
Keywords:mesoporous;Ce05Zr0jO2;mixedoxide;PEG4000;rraeearths
CLCnuInber:0643.3 Documentcode:A ArticleID:1002—
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