采用氧化钼精矿替代钼铁在316L不锈钢冶炼中应用研究.pdfVIP

采用氧化钼精矿替代钼铁在316L 不锈钢冶炼中的 应用研究 陈兴润 王建新 潘吉祥 白小军 田书武 徐斌 （酒泉钢铁（集团）有限责任公司，甘肃，嘉峪关，735100） 摘要 对氧化钼精矿替代钼铁在316L 不锈钢AOD 转炉的冶炼进行研究，通过氧化钼球的还原热力学条件分析，采用氧化钼 球和钼铁冶炼AOD 工艺参数及钢水纯净度对比，及氧化钼球成分、不同加入时机对AOD 钼的收得率的影响规律研究，得出在 316L 不锈钢的冶炼中采用氧化钼精矿替代钼铁是完成可行的；在AOD 转炉中加入氧化钼球，不影响冶炼工艺参数及钢水纯 净度，AOD 钼的收得率与加入钼铁冶炼钼的收得率相当，可有效降低冶炼成本；氧化钼球中高的CaO 含量对提高AOD 钼的收 得率有利；在加入量相同的情况下，C 含量为0.8％的阶段加入氧化钼球AOD 钼的收得率较高。 关键词 炼钢 氧化钼球 热力学 316L 不锈钢 收得率 The study of 316L stainless steel smelting by molybdenum oxide instead of ferromolybdenum Chen Xingrun Wang Jianxin Pan Jixiang Bai Xiaojun Tian Shuwu Xu Bin （Jiuquan Iron Steel (Group) Co.Ltd.,Jiayuguan,735100, Gansu ） Abstract The 316L stainless steel smelting by molybdenum oxide instead of ferromolybdenum were researched. The thermodynamic conditions of molybdenum oxide reduction were analyzed. The AOD process parameters and steel purity by molybdenum oxide smelting were compared with ferromolybdenum and the effect of molybdenum oxide content and various feeding modes on the molybdenum yield were analyzed. The results show that the 316L stainless steel smelting by molybdenum oxide instead of ferromolybdenum in AOD furnace is feasible; the molybdenum yield 、 the AOD process parameters and steel purity by molybdenum oxide smelting are almost same with ferromolybdenum smelting and the cost of smelting is reduced effectively; higher CaO content of molybdenum oxide is advantageous to obtain high molybdenum yield; the molybdenum oxide being added into the AOD with the carbon content of 0.8 ％can obtain higher yield at the same feeding amount. Key words steelmaking molybdenum oxide thermodynamics 316L stainless steel yield 1 前言 通常采用钼铁作为冶炼含钼合金钢的添加剂，但钼铁价格较高，冶金工作者开发了采用廉价的初级原