非对称陶瓷分离膜的制备和其性能研究.pdfVIP

J32 非对称陶瓷分离膜的制备及其性能研究 李元高 1 曾孟祥 1 洪昱斌 2 严滨 1 (1. 厦门理工学院 ，福建厦门 361024 ；2. 三达膜科技有限公司，福建厦门 361022) 摘要：采用纳米材料包裹 Al O 粉末，以低温固态烧结方式获得高性能的大尺寸非对称陶瓷分离膜，并研究了 0.2μm 2 3 非对称陶瓷分离膜产品性能，结果表明：该陶瓷膜纯水通量稳定在 3000 L/㎡·h 以上；孔径分布狭窄、精度高，基本 集中在 0.1-0.2μm 之间；膜层表面完整无缺陷；截留效果好；能满足绝大多数高腐蚀性、高温、高压环境下的分离过滤 要求。 [关键词] 纳米材料；固态烧结；非对称陶瓷分离膜；纯水通量 Preparation and properties of asymmetric ceramic membrane 1 1 2 1 Li yuangao ,Zeng mengxiang ,Hong yubin ,Yan bin (1.Xiamen University of Technology，FujianXiamen 361024 ；2.Suntar Membrance Technology Co.Ltd, FujianXiamen 361022) Abstract: Large-size and high-performance asymmetric ceramic membrane was produced by the low-temperature solid-state sintering method. The material was Al O powder packaged with nano-material. The property of 0.2μm 2 3 asymmetric ceramic membrane had also been studied. Results showed that: water flux of the ceramic membrane was stabled at more than 3000 L/㎡*h. Its pore size distribution was narrow and high precision which was concentrated in 0.1-0.2μm. The membrane surface was integrated without any defects. The entrapment was effective to satisfied most separation requirements in the high corrosion, high temperature and high pressure environment. [Keywords] nano-material ；solid-state sintering；high-performance asymmetric ceramic membrane ；water flux 1 前言 膜分离技术已经成为国际上公认的 21 世纪最具发展前途的生产、环保与节能技术之一。陶瓷膜 是以无机陶瓷材料经特殊工艺制备而形成的非对称膜，呈管状及多通道状，管壁密布微孔。由于具有 分离效率高、节约能源、耐热、耐腐蚀和结构稳定等突出优点，而受到人们的重视[1-3] 。但国内陶瓷膜 的支撑体大部分采用低熔点氧化物掺入氧化铝原料中，以液态烧结的方式实现较低温度下的支撑体烧 结，导致支撑体耐酸碱性较差，无法适应一些严苛的使用环境，同时液态烧结导致支撑体产生闭孔， 降低