低黏度含硅芳炔树脂的制备与性能.pdfVIP

12 娌 鐑ㄧ瓑锛氫綆榛忓害鍚鑺崇倲鏍戣剛鐨勫埗澶囦笌鎬ц兘 缁濈紭鏉愭枡 2015 锛?8(2) 浣庨粡搴﹀惈纭呰姵鐐旀爲鑴傜殑鍒跺涓庢€ц兘 娌 鐑紝瑭逛匠鏍嬶紝绔 鏃革紝琚佽崬榫欙紝榛勫彂鑽ｏ紝鏉 纾 锛堝崕涓滅悊宸ュぇ瀛 鏉愭枡绉戝涓庡伐绋嬪闄紝鐗圭鍔熻兘楂樺垎瀛愭潗鏂欏強鐩稿叧鎶€鏈暀鑲查儴閲嶇偣瀹為獙瀹わ紝涓婃捣 200237 锛 鎽樿锛氬湪鍚鑺崇倲鏍戣剛锛圥SA 锛変腑鍔犲叆娲绘€х█閲婂墏鍒跺浜嗕綆榛忓害鍚鑺崇倲鏍戣剛锛岀爺绌朵綆榛忓害PSA 鐨勬祦鍙樻€ц兘鍜 鍥哄寲宸ヨ壓锛屽浐鍖朠SA 鏍戣剛鐨勭儹鎬ц兘銆佸姏瀛︽€ц兘鍜岀數姘旀€ц兘銆傜粨鏋滆〃鏄庯細PSA 涓姞鍏ョ█閲婂墏鍙互鏄捐憲闄嶄綆鍏堕粡 搴︼紝PSA 鏍戣剛鍦ㄦ爱姘斿拰绌烘皵涓殑5%鐑け閲嶆俯搴﹀垎鍒彲杈?65.5 鈩冨拰603.3 鈩冿紝800 鈩冩畫鐣欑巼鍒嗗埆杈惧埌89.7%鍜 53.8% 锛汸SA 鏍戣剛鐨勭幓鐠冨寲杞彉娓╁害楂樹簬500 鈩冿紱鍔犲叆10%璐ㄩ噺鍒嗘暟绋€閲婂墏鐨凱SA 鏍戣剛鐨勫集鏇插己搴﹀彲杈惧埌 1 6 30 MPa 锛屽集鏇叉ā閲忓彉鍖栦笉澶э紝25 鈩冧笅鍦?0 ~ 10 Hz 鍐呬粙鐢靛父鏁板拰浠嬭川鎹熻€楄姝ｅ垏鍒嗗埆灏忎簬3.24 鍜?.005銆 鍏抽敭璇嶏細鍚鑺崇倲鏍戣剛锛涢粡搴︼紱鍥哄寲锛涘姏瀛︽€ц兘锛涗粙鐢垫€ц兘 涓浘鍒嗙被鍙凤細TM215 锛汿Q323 鏂囩尞鏍囧織鐮侊細A 鏂囩珷缂栧彿锛?009-9239锛?015 锛?2-0012-05 Preparation and Properties of Low Viscosity Silicon-containing Arylacetylene Resin Shen Ye, Zhan Jiadong, Tong Yang, Yuan Qiaolong, Huang Farong, Du Lei (Key Laboratory for Specially Functional Polymers and Related Technology of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China) Abstract: A low viscosity silicon-containing arylacetylene resin(PSA) was prepared by adding reactive dilu- ent to PSA, and the rheological property and curing process of the viscosity PSA, the thermal property, mechanical properties, and dielectric properties of the cured PSA were studied. The results show that the addition of reactive diluent to PSA could make its viscosity decrease siginificantly. The thermal decompo- sition temperatures at 5% weight loss of the cured PSA reach 665.5 鈩 in nitrogen and 603.3 鈩