再碱化条件下混凝土中钢筋表面锈蚀层组成变化.pdfVIP

第五届全国腐蚀大会论文集(2009年9 月14-17日,北京) 再碱化条件下混凝土中钢筋表面锈蚀层的 组成变化 1 1 1 1 2 2 张俊喜 张羽 鲁进亮 蒋俊 王昆 屈文俊 (1 上海电力学院电化学研究室，国家电力公司热力设备腐蚀与防护重点实验室，上海，200090 2 同济大学土木工程学院，上海，200090) 摘要：研究了带锈钢筋在再碱化过程中的电极表面电化学反应，采用扫描电子显微镜结合能 谱分析、电化学测量技术考察了再碱化条件下钢筋电极表面锈蚀层发生还原反应的可能性； 研究了不同电场下钢筋表面锈蚀层的还原情况。结果表明：再碱化过程中，钢筋电极表面锈 蚀层在再碱化过程中可以发生还原反应，但是还原所得的铁单质呈疏松的堆积状，很难使钢 筋进入钝化状态；而采用组合电场则可以改善钢筋表面的还原状态，形成致密的沉积层，有 利于钢筋进入钝化状态，研究结果显示：再碱化对带锈钢筋混凝土的修复同样具有较好的效 果，将大大拓宽再碱化修复的范围。 关键词：锈蚀层；还原；再碱化；碳化混凝土；钢筋 The transformation of rust formed on rebar in the concrete during realkalization treatment 1 1 1 1 2 2 Zhang Junxi , Zhang Yu Lu Jinliang , Jiang Jun , Wang Kun Qu Wenjun (1 Electrochemical Research Group, Shanghai University of Electric Power, Key Laboratory of State Power Corporation of China, Shanghai, 200090 2 College of Civil Engineering, Tongji University, Shanghai, 200090) Abstract: The electrochemical reactions on the rusted rebar during realkalization treatment were investigated by using scan electron microscopy with energy spectrum (SEM-EDAX) and electrochemical measurement. The feasibility of reduction of rust formed on rebar was researched. The depositions of Fe from rust layer under different electric field were observed using SEM with EDAX. Results show that the rust layer on the rebar can transform to metallic iron that was composed by fine iron crystalline grain and which made rebar difficult to transform into passivity. However, a compact iron deposit layer can form by using combinatorial electric field, and improve the anti-corrosion performance of rebar after realkalization treatment. All this show that the realkalization treatment not only rehabil