MgO%2fSi3N4复合材料表面致密层的形成.pdfVIP

MgO/Si N 复合材料表面致密层的形成 3 4 1） 2） 2） 1） 王林俊 孙加林 洪彦若 冯运生 1） 北京通达耐火技术股份有限公司 2） 北京科技大学无机非金属材料系 摘 要：在发现 MgO/Si N 复合材料氧化时其表面生成一层阻碍进一步氧化和提高抗侵蚀的致密层 3 4 的基础上，研究了添加 Al、Si 后形成的致密层的组成和结构，运用材料热力学研究其形成机理。 提出“转换氧分压”为衡量气态氧化物 SiO 和 Al O 稳定性的标准，并确定气态的 SiO 或 Al O 可 2 2 以在氧化层内部生成以及由于它们在表面的凝聚和反应使表层内形成了致密层的机理。 关键词：MgO/Si3N4， 复合材料， 耐火材料，致密层 Mechanism of Forming Compact Layer on the Surface of MgO/Si N Composite 3 4 Wang Linjun Sun Jialin Hong Yanruo Department of Inorganic and Nonmetallic Materials University of Science and Technology Beijing, Beijing 100083, China Abstract: A compact layer on the surface which is an anti-oxidation and anti-corrosion layer will be formed in MgO/Si3N4 composite in the process of oxidation was determined. On the basis of the determination the compositions and structure of compact layer after added Si or Al were studied, the mechanism of forming compact layer in the procession of adding Si or Al was studied too by material thermodynamics. The “Exchange Oxygen Partial Pressure” was proposed as a standard for evaluation the stability of gaseous SiO and Al2O. Using the thermodynamics and the standard that the gaseous SiO and Al2O will produce inside the composite and they will deposit and react with other oxides to form the compact layer in the procession of oxidation are determined. Keywords: MgO/Si N ，composite, refractory, compact layer. 3 4 1.前言 许多资料表明[1, 2] ，氧化物－非氧化物复合耐火材料在高温使用时，材料组分之 间或材料组分与 O2 之间发生反